English

Write Applications of Co-ordination Compounds in Medicine and Electroplating.

Advertisements
Advertisements

Question

Write applications of co-ordination compounds in medicine and electroplating.

Advertisements

Solution

Applications of coordination compounds:

1) In medicine:

  • Cisplatin [PtCl2(NH3)2] is useful in treatment of cancer.
  • EDTA is useful in treatment of poisoning by lead.

2) In electroplating

Stable complexes with very small dissociation in solution are used for electroplating with silver and gold.

  • The complex K[Ag(CN)2] is used for electroplating with silver
  • The complex K[Au(CN)2] is used for electroplating with gold
shaalaa.com
  Is there an error in this question or solution?
2012-2013 (October)

APPEARS IN

RELATED QUESTIONS

Classify the following ligands into monodentate and polydentate —

  1. Ammonia
  2. Carbon monoxide
  3. Ethylene diamine
  4. Ethylene diamine tetra acetate ion

Explain the following, giving two examples:

Coordination entity


What is meant by unidentate ligand?


Amongst the following, the most stable complex is:


IUPAC name of the following compound is

(a) 3 - Bromo- 3, 4- dimethylheptane

(b) 3, 4- dimethyl - 3- bromoheptane

(c) 5- Bromo- 4, 5- dimethylheptane

(d) 4, 5- dimethyl- 5- bromoheptane


Write IUPAC names of the following compounds


Write IUPAC names of the following compounds:


Write structures of compounds A, B and C in of the following reactions


Complete the following reactions

NH3+3Cl2(excess) ---->


Write the structures of compounds A, B and C in the following reactions:


Write the IUPAC name of the following coordination compound:

[Cr(NH3)4(H2O)2]Cl3


The ligand triethylenetetramine is _______.


What is the coordination number of chromium in \[\ce{[Cr(NH3)2(H2O2)2]Cl3}\]?


In which of the following compounds, the Central metal atom/ion is in the lowest oxidation state?


The stabilisation of coordination compounds due to chelation is called the chelate effect. Which of the following is the most stable complex species?


Identify the correct statements for the behaviour of ethane-1, 2-diamine as a ligand.

(i) It is a neutral ligand.

(ii) It is a didentate ligand.

(iii) It is a chelating ligand.

(iv) It is a unidentate ligand.


Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:

Column I (Compound) Column II (Oxidation state of Co)
A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] 1. + 4
B. \[\ce{[Co(NH3)4 CL2]SO4}\] 2. 0
C. \[\ce{Na4[Co(S2O3)3]}\] 3. + 1
D. \[\ce{[Co2(CO)8]}\] 4. + 2
  5. + 3

What is the relationship between observed colour of the complex and the wavelength of light absorbed by the complex?


The oxidation state of Fe in the brown ring complex [F3(H2O)5NO]SO4 is


What are Homoleptic complexes?


Why chelate complexes are more stable than complexes with unidentate ligands?


What are Heteroleptic complexes?


The one that will show optical activity is: (en = ethane 1, 2-diamine)


Which of the following species cannot act as a ligand? Give reason.


What is meant by the chelate effect? Give an example.


What is meant by the chelate effect? Give an example.


Give two examples of unidentate ligands.


What is meant by a didentate ligand?


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×