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प्रश्न
Explain the following, giving two examples:
Homoleptic
Explain a homoleptic complex with an example.
Explain with two examples of the following:
Homoleptic
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उत्तर
Homoleptic refers to a coordination complex where all the ligands attached to the central metal ion are the same type. For example:
- [Cu(NH3)4]2+: This is a homoleptic complex where all four ligands are ammonia (NH3) molecules, coordinated to the copper (Cu2+) ion.
- [NiCl6]2−: In this homoleptic complex, all six ligands are chloride (Cl−) ions, coordinated to the nickel (Ni2−) ion.
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संबंधित प्रश्न
Explain the following, giving two examples:
Coordination entity
What is the coordination entity formed when excess of aqueous KCN is added to an aqueous solution of copper sulphate? Why is it that no precipitate of copper sulphide is obtained when H2S(g) is passed through this solution?
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
cis-[CrCl2(en)2]Cl
Give the oxidation state, d-orbital occupation and coordination number of the central metal ion in the following complex:
(NH4)2[CoF4]
Which of the following compounds is used as a semipermeable membrane?
(a) Potassium ferrocyanide
(b) Potassium argentocyanide
(c) Sodium meta aluminate
(d) Copper ferrocyanide
IUPAC name of the following compound is
(a) 3 - Bromo- 3, 4- dimethylheptane
(b) 3, 4- dimethyl - 3- bromoheptane
(c) 5- Bromo- 4, 5- dimethylheptane
(d) 4, 5- dimethyl- 5- bromoheptane
How is Benzonitrile converted to Benzophenone?
Write structures of compounds A, B and C in of the following reactions
Write IUPAC name of the following Complex [Cr(NH3)3Cl3]
Write the IUPAC name of the following coordination compound:
[Cr(NH3)4(H2O)2]Cl3
Ligand (en) is an example of ___________.
A group of atoms can function as a ligand only when:
The coordination number of Cr in [Cr(NH3)3(H2O)3]Cl3 is ___________.
The oxidation number of Fe in K4[Fe(CN)6] is ____________.
The coordination number of the central ion may be obtained from:
Which of the following is non-ionizable?
In which of the following compounds, the Central metal atom/ion is in the lowest oxidation state?
When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.
When 1 mol \[\ce{CrCl3.6H2O}\] is treated with excess of \[\ce{AgNO3}\], 3 mol of \[\ce{AgCl}\] are obtained. The formula of the complex is ______.
The correct \[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2Cl2]}\] is ______.
Which of the following complexes are heteroleptic?
(i) \[\ce{[Cr(NH3)6]^{3+}}\]
(ii) \[\ce{[Fe(NH3)4]Cl2]^+}\]
(iii) \[\ce{[Mn(CN)6]^{4-}}\]
(iv) \[\ce{[Co(NH3)4]Cl2]}\]
A coordination compound \[\ce{CrCl3.4H2O}\] precipitates silver chloride when treated with silver nitrate. The molar conductance of its solution corresponds to a total of two ions. Write structural formula of the compound and name it.
A complex of the type \[\ce{[M(AA)2X2]^{n+}}\] is known to be optically active. What does this indicate about the structure of the complex? Give one example of such complex.
Assertion: \[\ce{Cr(H2O)6]Cl2 and [Fe(H2O)6]Cl2}\] are reducing in nature.
Reason: Unpaired electrons are present in their d-orbitals.
Oxidation number of cobalt in K[Co(CO)4] is
The nature of hybridisation in the ammonia molecule is
Which of the following is an ionic ligand?
The oxidation state of Fe in the brown ring complex [F3(H2O)5NO]SO4 is
The co-ordinate number and the oxidation state of the element E in the complex [E(en)2(C2O4)]NO2 are respectively?
The oxidation number d-arbitral occupation and co-ordination number of Cr in the complex cis [Cr(en)2Cl2]Cl are respectively.
The most stable ion is ______.
Metal attached with EDTA in an octahedral complex, has coordination number ______.
Total sodium ions which are present in one formula unit of sodium ethane-1, 2-diaminetetraacetatochromate (II) and sodium hexanitrito cobaltate (III) are ______.
What is a chelate complex?
Which of the following species cannot act as a ligand? Give reason.
What is meant by the chelate effect? Give an example.
What is meant by the chelate effect? Give an example.
What is meant by the chelate effect? Give an example.
Explain with two examples of the following:
Ligand
Give two examples of ambidentate ligands.
