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प्रश्न
Explain the following, giving two examples:
Homoleptic
Explain a homoleptic complex with an example.
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उत्तर
Homoleptic refers to a coordination complex where all the ligands attached to the central metal ion are the same type. For example:
- [Cu(NH3)4]2+: This is a homoleptic complex where all four ligands are ammonia (NH3) molecules, coordinated to the copper (Cu2+) ion.
- [NiCl6]2−: In this homoleptic complex, all six ligands are chloride (Cl−) ions, coordinated to the nickel (Ni2+) ion.
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संबंधित प्रश्न
Write the structure and IUPAC names of all the metamers represented by formula C4H10
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(a) Potassium ferrocyanide
(b) Potassium argentocyanide
(c) Sodium meta aluminate
(d) Copper ferrocyanide
Write IUPAC names of the following compounds
Write IUPAC names of the following compounds:
Write structures of compounds A, B and C in of the following reactions
Write structures of compounds A, B and C in of the following reactions
Write the IUPAC name of the following complex:
[Co(NH3)5(CO3)]Cl
Write the structures of compounds A, B and C in the following reactions:
Write structures of compounds A and B of the following reaction :
The coordination number of Cr in [Cr(NH3)3(H2O)3]Cl3 is ___________.
The oxidation number of Fe in K4[Fe(CN)6] is ____________.
What is the coordination number of chromium in \[\ce{[Cr(NH3)2(H2O2)2]Cl3}\]?
In which of the following compounds, the Central metal atom/ion is in the lowest oxidation state?
When 0.1 mol \[\ce{CoCl3 (NH3)5}\] is treated with excess of \[\ce{AgNO3}\], 0.2 mol of \[\ce{AgCl}\] are obtained. The conductivity of solution will correspond to ______.
The correct \[\ce{IUPAC}\] name of \[\ce{[Pt(NH3)2Cl2]}\] is ______.
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Match the complex ions given in Column I with the colours given in Column II and assign the correct code:
| Column I (Complex ion) | Column II (Colour) |
| A. \[\ce{[Co(NH3)6]^{3+}}\] | 1. Violet |
| B. \[\ce{[Ti(H2O)6]^{3+}}\] | 2. Green |
| C. \[\ce{[Ni(H2O)6]^{2+}}\] | 3. Pale blue |
| D. \[\ce{(Ni(H2O)4 (en)]^{2+} (aq)}\] | 4. Yellowish orange |
| 5. Blue |
Match the coordination compounds given in Column I with the central metal atoms given in Column II and assign the correct code:
| Column I (Coordination Compound) | Column II (Central metal atom) |
| A. Chlorophyll | 1. rhodium |
| B. Blood pigment | 2. cobalt |
| C. Wilkinson catalyst | 3. calcium |
| D. Vitamin B12 | 4. iron |
| 5. magnesium |
Match the compounds given in Column I with the oxidation state of cobalt present in it (given in Column II) and assign the correct code:
| Column I (Compound) | Column II (Oxidation state of Co) |
| A. \[\ce{[Co(NCS)(NH3)5](SO3)}\] | 1. + 4 |
| B. \[\ce{[Co(NH3)4 CL2]SO4}\] | 2. 0 |
| C. \[\ce{Na4[Co(S2O3)3]}\] | 3. + 1 |
| D. \[\ce{[Co2(CO)8]}\] | 4. + 2 |
| 5. + 3 |
Oxidation number of cobalt in K[Co(CO)4] is
The nature of hybridisation in the ammonia molecule is
Oxidation number of carbon in CH2Cl2 is
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The oxidation state of Fe in the brown ring complex [F3(H2O)5NO]SO4 is
Which one of the following ligands forms a chelate?
The most stable ion is ______.
Metal attached with EDTA in an octahedral complex, has coordination number ______.
Ethylene diamine tetraacetate (EDTA) ion is ______.
What are Homoleptic complexes?
Given below are two statements.
Statement I: In CuSO4·5H2O, Cu-O bonds are present.
Statement II: In CuSO4·5H2O, ligands coordinating with Cu(II) ion are O- and S-based ligands.
In light of the above statement, choose the correct answer from the options given below.
Total sodium ions which are present in one formula unit of sodium ethane-1, 2-diaminetetraacetatochromate (II) and sodium hexanitrito cobaltate (III) are ______.
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\[\ce{[V(CN)6]^{4-}, [Fe(CN)6]^{4-}, [Ru(NH3)6]^{3+} and [Cr(NH3)6]^2}\] is:
Does ionization isomer for the following compound exist? Justify your answer.
\[\ce{Hg[Co(SCN)4]}\]
What is meant by the chelate effect? Give an example.
What is meant by the chelate effect? Give an example.
What is meant by the chelate effect? Give an example.
In the complex ion \[\ce{[CoCl(en)2ONO]+}\], the coordination number and the oxidation number of the central metal ion are ______ and ______.
Explain the following, giving two examples:
Coordination polyhedron
Give two examples of didentate ligands.
Statement I: [Co(NH3)6]3+ is a homoleptic compleх whereas [Co(NH3)4Cl2]+ is a heteroleptic complex.
Statement II: Complex [Co(NH3)6]3+ has only one kind of ligands but [Co(NH3)4Cl2]+ has more than one kind of ligands.
In the light of the above statements, Choose the correct answer form the options given below.
Homoleptic complex from the following complex is ____.
