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Questions
Write reactions to bring about the following conversions.
Acetamide to Ethylamine
Convert, acetamide into ethyl amine.
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Solution
\[\ce{CH3CONH2 ->[LiAH4][ether] CH3CH2NH2}\]
\[\ce{CH3CONH2 + 4[H] ->[LiAH4][ether] CH3CH2NH2 + H2O}\]
RELATED QUESTIONS
Write a short note on Hoffmann bromamide degradation.
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Hoffmann-bromamide degradation reaction
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Answer in one sentence.
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\[\ce{CH3-CN ->[Na/C2H5OH]}\]
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Given below are two statements labelled as Assertion (A) and Reason (R).
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Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.
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In order to prepare a 1° amine from an alkyl halide with simultaneous addition of one \[\ce{CH2}\] group in the carbon chain, the reagent used as source of nitrogen is ______.
The best reagent for converting 2–phenylpropanamide into 2-phenylpropanamine is ______.
The best reagent for converting, 2-phenylpropanamide into 1- phenylethanamine is ______.
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Which of the following compounds is the weakest Brönsted base?
Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?
(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].
(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].
What is the best reagent to convert nitrile to primary amine?
Write following conversions:
acetanilide `->` p-nitroaniline
How will you carry out the following conversions?
Assertion: Hoffmann’s bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.
Assertion: Aromatic 1° amines can be prepared by Gabriel Phthalimide Synthesis.
Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.
Account for the following:
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Reduction of nitro alkanes yields which compound?
In the given reaction what is the X?
\[\begin{array}{cc}
\ce{O}\phantom{.......................}\\
||\phantom{.......................}\\
\phantom{}\ce{R - C - OH <-[H3O] Χ ->[H] RCH2NH2}
\end{array}\]
Which of the following CANNOT be prepared by ammonolysis of alkyl halide?
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Which of the following would not be a good choice for reducing nitrobenzene to aniline?
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Write short note on the following:
Ammonolysis
Write a short note on Ammonolysis.
Write a short note on the following:
Ammonolysis.
Write a short note on the following:
Ammonolysis
