Advertisements
Advertisements
Question
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]
Advertisements
Solution
\[\ce{\underset{chloride}{\underset{Benzenediazonium}{C6H5N2Cl}} ->[CuCN] \underset{(A)}{\underset{Cyanobenzene}{C6H5CN}} ->[H2O/H+] \underset{(B)}{\underset{Benzoic acid}{C6H5COOH}} ->[NH3][\Delta] \underset{(C)}{\underset{Benzamide}{C6H5CONH2}}}\]
APPEARS IN
RELATED QUESTIONS
How are propan-1-amine and propan-2-amine prepared from oxime?
Write a short note on Hoffmann bromamide degradation.
Accomplish the following conversion:
Nitrobenzene to benzoic acid
Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :

Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
Name the process of breaking C-X bond by ammonia in preparation of amines.
Acetamide on reduction using Na/C2H5OH gives ____________.
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
Which of the following amines exhibits maximum degree of intermolecular hydrogen bonding?

Identify the major product (B).
Benzylamine may be alkylated as shown in the following equation:
\[\ce{C6H5CH2NH2 + R - X -> C6H5CH2NHR}\]
Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?
The best reagent for converting 2–phenylpropanamide into 2-phenylpropanamine is ______.
Among the following amines, the strongest Brönsted base is:
Reduction of nitrobenzene by which of the following reagent gives aniline?
(i) \[\ce{Sn/HCl}\]
(ii) \[\ce{Fe/HCl}\]
(iii) \[\ce{H2 - Pd}\]
(iv) \[\ce{Sn/NH4OH}\]
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
Write following conversions:
nitrobenzene `->` acetanilide
The Gabriels' phthalimide synthesis is used in the synthesis of
Reduction of nitro alkanes yields which compound?
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
Write a short note on Ammonolysis.
