Advertisements
Advertisements
Question
Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
Advertisements
Solution
Ethyl cyanide (or Propanenitrile) \[\ce{C2H5 - CN}\] after treatment with sodium and alcohol (ethanol) produces n-propyl amine.
\[\ce{\underset{(Ethyl cyanide)}{CH3 - CH2 - CN} ->[Na/C2H5OH] \underset{(n-Propyl amine)}{CH3 - CH2 - CH2 - NH2}}\]
The above reduction is known as the Mendius reduction.
APPEARS IN
RELATED QUESTIONS
Write the chemical equation involved in the following reaction:
Hoffmann-bromamide degradation reaction
How do you convert the following: C6H5CONH2 to C6H5NH2
Accomplish the following conversion:
Benzamide to toluene
Give the structures of A, B and C in the following reaction:
\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]
Give the structures of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}\]
Mention 'two' uses of propan-2-one.
Give the structures of A, B and C in the following reactions :

Give the structures of A, B and C in the following reactions :

Account for the following:
Gabriel phthalimide synthesis is not preferred for preparing aromatic primary amines.
Answer in one sentence.
Predict the product of the following reaction.
\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]
Answer the following
Identify A and B in the following reactions.
\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]
Mendius reaction is used to convert _____________
Write the order of reactivity of alkyl halides with ammonia.
Write reactions to bring about the following conversions.
Acetamide to methylamine
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Explain the following reaction with a suitable example.
Hofmann elimination reaction
Identify compound 'B' in following series of reactions?
\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
The end product C of the following reaction is
\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]
\[\ce{CH3-CN ->[Na/C2H5OH]}\]
The product formed is ____________.
Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?
Identify the INCORRECT statement regarding Hofmann bromamide reaction.
Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?
Identify product B in the following reaction.
\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]
Which of the following does NOT give carbylamine test?
Benzylamine may be alkylated as shown in the following equation:
\[\ce{C6H5CH2NH2 + R - X -> C6H5CH2NHR}\]
Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?
Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.
Which of the following compounds is the weakest Brönsted base?
Which of the following amines can be prepared by Gabriel synthesis.
(i) Isobutyl amine
(ii) 2-Phenylethylamine
(iii) N-methylbenzylamine
(iv) Aniline
How will you bring out the following conversion?

How will you carry out the following conversion?

Describe Gabriel's phthalimide synthesis. (Give reaction)
The Gabriels' phthalimide synthesis is used in the synthesis of
Reduction of nitro alkanes yields which compound?
Acetamide and ethyl amide can be distinguished by reacting with.
Which of the following compound is expected to be most basic?
Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?
Methyl amine on reaction with chloroform in the presence of NaOH gives ______.
Which of the following amines can be prepared by Gabriel phthalimide reaction?
- Phenyl methenamine
- N, N - Dimethylaniline
- N - Methyl aniline
- Benzenamine
Choose the correct order of the basic nature of the above amines.
The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is ______.
What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?
Write the name of the product formed by the action of LiAlH4/ether on acetamide.
Write short note on the following:
Ammonolysis
Write a short note on the following:
Ammonolysis
Write a short note on Ammonolysis.
Write short note on the following:
Ammonolysis
Write short note on the following.
Ammonolysis.
Write short notes on the following:
Ammonolysis
Write a short note on the following:
Ammonolysis
