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Karnataka Board PUCPUC Science 2nd PUC Class 12

Accomplish the following conversion: Benzamide to toluene

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Question

Accomplish the following conversion:

Benzamide to toluene

Chemical Equations/Structures
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Solution

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Chapter 9: Amines - Exercises [Page 279]

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NCERT Chemistry Part 1 and 2 [English] Class 12
Chapter 9 Amines
Exercises | Q 9.8 (viii) | Page 279

RELATED QUESTIONS

How do you convert the following: C6H5CONH2 to C6H5NH2


Give the structure of A, B and C in the following reaction:

\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]


Answer in one sentence.

Which amide does produce ethanamine by Hofmann bromamide degradation reaction?


Explain Hoffmann’s exhaustive alkylation with suitable reactions.


Explain the following reaction with a suitable example.

Hofmann elimination reaction


Which of the following reactions is appropriate for converting benzamide to aniline?


Which of the following reagents is used in Hofmann's elimination reaction of amines?


Which of the following reactions does NOT yield an amine?


Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:


Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine?


Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.


Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?

(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].

(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].


Write following conversions:

acetanilide `->` p-nitroaniline


How will you bring out the following conversion?


How will you carry out the following conversions?


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Reason: Primary amines are more basic than secondary amines.


  1. Phenyl methenamine
  2. N, N - Dimethylaniline
  3. N - Methyl aniline
  4. Benzenamine

Choose the correct order of the basic nature of the above amines.


Which of the following would not be a good choice for reducing nitrobenzene to aniline?


Assertion: Amimonolysis of alkyl halides involves the reaction between alkyl halides and alcoholic ammonia.

Reason: Ammonolysis of alkyl halides produces secondary amines only.


Write a short note on the following:

Ammonolysis.


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