Advertisements
Advertisements
Question
Assertion: Hoffmann’s bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.
Options
Both assertion and reason are wrong.
Both assertion and reason are correct statements but reason is not correct explanation of assertion.
Assertion is correct statement but reason is wrong statement.
Both assertion and reason are correct statements and reason is correct explanation of assertion.
Assertion is wrong statement but reason is correct statement.
Advertisements
Solution
Assertion is correct statement but reason is wrong statement.
Explanation:
Hofmann’s bromamide reaction is given by amides, not by amines. Moreover, primary amines are basic than secondary amines.
APPEARS IN
RELATED QUESTIONS
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Write the reaction of aliphatic primary amine with nitrous acid.
Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :

Choose the most correct option.
Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.
What is the molar mass of the amine formed when acetamide undergoes Hofmann bromamide degradation?
\[\ce{CH3-CN ->[Na/C2H5OH]}\]
The product formed is ____________.
Which of the following does NOT give carbylamine test?
Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?
Which of the following amines can be prepared by Gabriel synthesis.
(i) Isobutyl amine
(ii) 2-Phenylethylamine
(iii) N-methylbenzylamine
(iv) Aniline
Identify A and B in the following reaction.

How will you bring out the following conversion?

How will you carry out the following conversions?

Which of the following amines can be prepared by Gabriel phthalimide reaction?
What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?
Identify the product ‘C’ in the following reaction.
\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]
Write a short note on the following:
Ammonolysis
Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
Write a short note on the following:
Ammonolysis.
