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Assertion: Hoffmann’s bromamide reaction is given by primary amines. Reason: Primary amines are more basic than secondary amines. - Chemistry

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प्रश्न

Assertion: Hoffmann’s bromamide reaction is given by primary amines.

Reason: Primary amines are more basic than secondary amines.

विकल्प

  • Both assertion and reason are wrong.

  • Both assertion and reason are correct statements but reason is not correct explanation of assertion.

  • Assertion is correct statement but reason is wrong statement.

  • Both assertion and reason are correct statements and reason is correct explanation of assertion.

  • Assertion is wrong statement but reason is correct statement.

MCQ
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उत्तर

Assertion is correct statement but reason is wrong statement.

Explanation:

Hofmann’s bromamide reaction is given by amides, not by amines. Moreover, primary amines are basic than secondary amines.

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अध्याय 13: Amines - Multiple Choice Questions (Type - I) [पृष्ठ १९२]

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एनसीईआरटी एक्झांप्लर Chemistry [English] Class 12
अध्याय 13 Amines
Multiple Choice Questions (Type - I) | Q 69 | पृष्ठ १९२

संबंधित प्रश्न

Mention 'two' uses of propan-2-one.


Give the structures of A, B and C in the following reactions :


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Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?


Answer the following

Explain Gabriel phthalimide synthesis.


Answer the following

Explain the ammonolysis of alkyl halides.


Write reactions to prepare ethanamine from Acetonitrile.


Name the process of breaking C-X bond by ammonia in preparation of amines.


Write the order of reactivity of alkyl halides with ammonia.


Write reactions to bring about the following conversions.

Acetamide to methylamine


Explain Hoffmann’s exhaustive alkylation with suitable reactions.


Which of the following amines exhibits maximum degree of intermolecular hydrogen bonding?


Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:


Write following conversions:

nitrobenzene `->` acetanilide


Match the reactions given in Column I with the statements given in Column II.

  Column I   Column II
(i) Ammonolysis (a) Amine with lesser number of carbon atoms
(ii) Gabriel phthalimide synthesis (b) Detection test for primary amines.
(iii) Hoffmann Bromamide reaction (c) Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\]
(iv) Carbylamine reaction (d) Reaction of alkylhalides with \[\ce{NH3}\]

Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?


What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?


Identify the product ‘C’ in the following reaction.

\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]


Write short note on the following:

Ammonolysis


Assertion: Amimonolysis of alkyl halides involves the reaction between alkyl halides and alcoholic ammonia.

Reason: Ammonolysis of alkyl halides produces secondary amines only.


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