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प्रश्न
Assertion: Hoffmann’s bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.
विकल्प
Both assertion and reason are wrong.
Both assertion and reason are correct statements but reason is not correct explanation of assertion.
Assertion is correct statement but reason is wrong statement.
Both assertion and reason are correct statements and reason is correct explanation of assertion.
Assertion is wrong statement but reason is correct statement.
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उत्तर
Assertion is correct statement but reason is wrong statement.
Explanation:
Hofmann’s bromamide reaction is given by amides, not by amines. Moreover, primary amines are basic than secondary amines.
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संबंधित प्रश्न
Give the structures of A, B and C in the following reactions :

Give the structures of A, B and C in the following reaction:
\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]
Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :

Answer the following
Explain the ammonolysis of alkyl halides.
Identify product B in the following reaction.
\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]
Which of the following does NOT give carbylamine test?
Benzylamine may be alkylated as shown in the following equation:
\[\ce{C6H5CH2NH2 + R - X -> C6H5CH2NHR}\]
Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?
The source of nitrogen in Gabriel synthesis of amines is ______.
Among the following amines, the strongest Brönsted base is:
Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?
Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?
(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].
(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
Account for the following:
Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.
Which of the following reactions will not give a primary amine?
Which of the following compound is expected to be most basic?
- Phenyl methenamine
- N, N - Dimethylaniline
- N - Methyl aniline
- Benzenamine
Choose the correct order of the basic nature of the above amines.
Write short note on the following:
Ammonolysis
Write a short note on the following:
Ammonolysis
Write short notes on the following:
Ammonolysis
