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प्रश्न
Mendius reaction is used to convert _____________
विकल्प
amide into amine
alkyl halide into amine
nitroalkane into amine
alkyl cyanide into amine
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उत्तर
Mendius reaction is used to convert alkyl cyanide into amine
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संबंधित प्रश्न
An aromatic compound 'A' of molecular formula C7H7ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions :
Give the structures of A, B and C in the following reactions :
Write a short note on the following:
Hoffmann’s bromamide reaction
Accomplish the following conversion:
Nitrobenzene to benzoic acid
Accomplish the following conversion:
Benzamide to toluene
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]
Write the reaction of aromatic primary amine with nitrous acid.
Mention 'two' uses of propan-2-one.
Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
Answer in one sentence.
Which amide does produce ethanamine by Hofmann bromamide degradation reaction?
Explain Hoffmann’s exhaustive alkylation with suitable reactions.
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Explain the following reaction with a suitable example.
Hofmann elimination reaction
Identify the product 'A' in the following reaction.
\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]
The end product C of the following reaction is
\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]
Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.
Identify the major product (B).
____________ can be prepared exclusively by Gabriel phthalimide synthesis.
Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?
The reduction of alkyl cyanide with sodium and ethanol to give primary amines is, ____________.
Which of the following reagents is used in Mendius reduction reaction of alkyl cyanide?
Which of the following does NOT give carbylamine test?
Which of the following reactions does NOT yield an amine?
Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:
Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine?
The source of nitrogen in Gabriel synthesis of amines is ______.
Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.
The best reagent for converting 2–phenylpropanamide into 2-phenylpropanamine is ______.
Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.
Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is ______.
Reduction of nitrobenzene by which of the following reagent gives aniline?
(i) \[\ce{Sn/HCl}\]
(ii) \[\ce{Fe/HCl}\]
(iii) \[\ce{H2 - Pd}\]
(iv) \[\ce{Sn/NH4OH}\]
Which of the following amines can be prepared by Gabriel synthesis.
(i) Isobutyl amine
(ii) 2-Phenylethylamine
(iii) N-methylbenzylamine
(iv) Aniline
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
Identify A and B in the following reaction.
How will you carry out the following conversion?
How will you carry out the following conversions?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Which of the following compound is expected to be most basic?
When primary amines are treated with HCl, the product obtained is which of the following?
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?
Which of the following amines can be prepared by Gabriel phthalimide reaction?
Which of the following would not be a good choice for reducing nitrobenzene to aniline?
Write short note on the following:
Ammonolysis
Identify the compo ds A and B in the following reactions:
\[\ce{A ->[Nitrating mixture] B ->[(i) Sn/cone. HCI][(ii) NaOH] Aniline}\]
Write a short note on the following:
Ammonolysis
Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
Write a short note on Ammonolysis.
