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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Give the structures of A, B and C in the following reaction. {C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}

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प्रश्न

Give the structures of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}\]

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उत्तर

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अध्याय 9: Amines - Exercises [पृष्ठ २७९]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
अध्याय 9 Amines
Exercises | Q 9.9 (vi) | पृष्ठ २७९

संबंधित प्रश्न

Write the chemical equation involved in the following reaction:

Hoffmann-bromamide degradation reaction


Give the structures of A, B and C in the following reactions :


Write a short note on the following:

Hoffmann’s bromamide reaction


Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]


Give a plausible explanation for the following:

Why are amines less acidic than alcohols of comparable molecular masses?


Answer in one sentence.

Which amide does produce ethanamine by Hofmann bromamide degradation reaction?


Answer the following

Identify A and B in the following reactions.

\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]


Answer the following

Explain the ammonolysis of alkyl halides.


Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?


Quaternary ammonium salt is formed:


Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is ______.


Reduction of nitrobenzene by which of the following reagent gives aniline?

(i) \[\ce{Sn/HCl}\]

(ii) \[\ce{Fe/HCl}\]

(iii) \[\ce{H2 - Pd}\]

(iv) \[\ce{Sn/NH4OH}\]


Assertion: Aromatic 1° amines can be prepared by Gabriel Phthalimide Synthesis.

Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.


Describe Gabriel's phthalimide synthesis. (Give reaction)


Account for the following:

Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.


The Gabriels' phthalimide synthesis is used in the synthesis of


A primary amine is formed by an amide on treatment with bromine and alkali. The primary amine has


Acetamide and ethyl amide can be distinguished by reacting with.


Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?


Write a short note on the following:

Ammonolysis.


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