हिंदी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.

Advertisements
Advertisements

प्रश्न

Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.

विकल्प

  • \[\ce{2° R - Br + NH3}\]

  • \[\ce{2° R - Br + NaCN followed by H2 /Pt}\]

  • \[\ce{1° R - NH2 + RCHO followed by H2/Pt}\]

  • \[\ce{1° R - Br (2 mol) + potassium phthalimide followed by H3O+/heat}\]

MCQ
रिक्त स्थान भरें
Advertisements

उत्तर

Amongst the given set of reactants, the most appropriate for preparing 2° amine is \[\ce{1° R - NH2 + RCHO followed by H2/Pt}\].

Explanation:

\[\ce{\underset{1° Amine}{R - NH2} + \underset{Aldehyde}{O = HCR} ->[Reductive][amination] R - N - CHR ->[H2/Pt][Reduction] \underset{2° Amine}{RNH - CH2R}}\]

shaalaa.com
  क्या इस प्रश्न या उत्तर में कोई त्रुटि है?
अध्याय 13: Amines - Multiple Choice Questions (Type - I) [पृष्ठ १८१]

APPEARS IN

एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 13 Amines
Multiple Choice Questions (Type - I) | Q 9 | पृष्ठ १८१

संबंधित प्रश्न

Write a short note on Hoffmann bromamide degradation.


Write the chemical equation involved in the following reaction:

Hoffmann-bromamide degradation reaction


Answer in one sentence.

Predict the product of the following reaction.

\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]


The end product C of the following reaction is

\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]


Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.


Identify the major product (B).


Which nitrogen containing compound amongst the following would undergo Mendius reduction to furnish primary amine \[\ce{(R - NH2)}\]?


Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?


Identify product B in the following reaction.

\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]


Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:


Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.


Suggest a route by which the following conversion can be accomplished.


Identify A and B in the following reaction.


How will you carry out the following conversion?


Assertion: Hoffmann’s bromamide reaction is given by primary amines.

Reason: Primary amines are more basic than secondary amines.


The Gabriels' phthalimide synthesis is used in the synthesis of


A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.


The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is ______.


Identify A and B in the following reaction.

\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×