मराठी
कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.

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प्रश्न

Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.

पर्याय

  • \[\ce{2° R - Br + NH3}\]

  • \[\ce{2° R - Br + NaCN followed by H2 /Pt}\]

  • \[\ce{1° R - NH2 + RCHO followed by H2/Pt}\]

  • \[\ce{1° R - Br (2 mol) + potassium phthalimide followed by H3O+/heat}\]

MCQ
रिकाम्या जागा भरा
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उत्तर

Amongst the given set of reactants, the most appropriate for preparing 2° amine is \[\ce{1° R - NH2 + RCHO followed by H2/Pt}\].

Explanation:

\[\ce{\underset{1° Amine}{R - NH2} + \underset{Aldehyde}{O = HCR} ->[Reductive][amination] R - N - CHR ->[H2/Pt][Reduction] \underset{2° Amine}{RNH - CH2R}}\]

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पाठ 13: Amines - Multiple Choice Questions (Type - I) [पृष्ठ १८१]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
पाठ 13 Amines
Multiple Choice Questions (Type - I) | Q 9 | पृष्ठ १८१

संबंधित प्रश्‍न

Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis


 Write structures of compounds A and B in each of the following reactions:


Answer the following

Identify A and B in the following reactions.

\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]


The following amines is the product of Gabriel phthalimide synthesis.


Identify compound 'B' in following series of reactions?

\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]


What is the molar mass of the amine formed when acetamide undergoes Hofmann bromamide degradation?


Which of the following reactions does NOT yield an amine?


Given below are two statements labelled as Assertion (A) and Reason (R).

Assertion (A): Alkyl halides are insoluble in water.

Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.

Select the most appropriate answer from the options given below:


In order to prepare a 1° amine from an alkyl halide with simultaneous addition of one \[\ce{CH2}\] group in the carbon chain, the reagent used as source of nitrogen is ______.


Reduction of nitrobenzene by which of the following reagent gives aniline?

(i) \[\ce{Sn/HCl}\]

(ii) \[\ce{Fe/HCl}\]

(iii) \[\ce{H2 - Pd}\]

(iv) \[\ce{Sn/NH4OH}\]


How will you carry out the following conversions?


Assertion: Aromatic 1° amines can be prepared by Gabriel Phthalimide Synthesis.

Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.


The Gabriels' phthalimide synthesis is used in the synthesis of


Which of the following reactions will not give a primary amine?


Reduction of nitro alkanes yields which compound?


Which of the following compound gives pink colour on reaction with phthalic anhydride in cone. H2SO4 followed by treatment with NaOH?


Methyl amine on reaction with chloroform in the presence of NaOH gives ______.


Write short note on the following:

Ammonolysis


Identify A and B in the following reaction.

\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]


Write a short note on Ammonolysis.


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