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Answer in one sentence. Which amide does produce ethanamine by Hofmann bromamide degradation reaction?

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Answer in one sentence.

Which amide does produce ethanamine by Hofmann bromamide degradation reaction?

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उत्तर

Propanamide (C2H5CONH2) produces ethanamine by Hofmann bromamide degradation reaction.

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अध्याय 13: Amines - Exercises [पृष्ठ २९७]

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बालभारती Chemistry [English] Standard 12 Maharashtra State Board
अध्याय 13 Amines
Exercises | Q 2.03 | पृष्ठ २९७

संबंधित प्रश्न

Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis


How do you convert the following: Ethanenitrile to ethanamine


Write a short note on the following:

Hoffmann’s bromamide reaction


Accomplish the following conversion:

Nitrobenzene to benzoic acid


Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]


Give the structure of A, B and C in the following reaction:

\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]


Give the structure of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]


Give the structures of A, B and C in the following reaction:

\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]


Give the structures of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}\]


Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?


Write the reaction of aromatic primary amine with nitrous acid.


Choose the most correct option.

Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?


Answer the following

Identify A and B in the following reactions.

\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]


Answer the following

Write a reaction to convert acetic acid into methylamine.


Answer the following

Explain Gabriel phthalimide synthesis.


Write reactions to prepare ethanamine from Acetonitrile.


The following amines is the product of Gabriel phthalimide synthesis.


Write the order of reactivity of alkyl halides with ammonia.


Write reactions to bring about the following conversions.

Acetamide to Ethylamine


Write reactions to bring about the following conversions.

Acetamide to methylamine


Explain Hoffmann’s exhaustive alkylation with suitable reactions.


Identify compound 'B' in following series of reactions?

\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]


The end product C of the following reaction is

\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]


____________ can be prepared exclusively by Gabriel phthalimide synthesis.


What product is formed when \[\ce{R - C ≡ N}\] is hydrolysed?


What is the molar mass of the amine formed when acetamide undergoes Hofmann bromamide degradation?


\[\ce{CH3-CN ->[Na/C2H5OH]}\]

The product formed is ____________.


Which of the following reactions is appropriate for converting benzamide to aniline?


Identify 'A' and 'B' in the following conversions.

\[\ce{CH3 - I ->[Alc. KCN][\Delta] A ->[Na/C2H5OH] B}\]


Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?


Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:


Quaternary ammonium salt is formed:


Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.


Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.


Among the following amines, the strongest Brönsted base is:


Which of the following amines can be prepared by Gabriel synthesis.

(i) Isobutyl amine

(ii) 2-Phenylethylamine

(iii) N-methylbenzylamine

(iv) Aniline


Which of the following reactions are correct?

(i)

(ii)

(iii)

(iv)


What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?


Suggest a route by which the following conversion can be accomplished.


Match the reactions given in Column I with the statements given in Column II.

  Column I   Column II
(i) Ammonolysis (a) Amine with lesser number of carbon atoms
(ii) Gabriel phthalimide synthesis (b) Detection test for primary amines.
(iii) Hoffmann Bromamide reaction (c) Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\]
(iv) Carbylamine reaction (d) Reaction of alkylhalides with \[\ce{NH3}\]

Assertion: Hoffmann’s bromamide reaction is given by primary amines.

Reason: Primary amines are more basic than secondary amines.


Which of the following reactions will not give a primary amine?


The compound X is which of the following?

\[\ce{CH3CN ->[Na + C2H5OH] x}\]


In the given reaction what is the X?

\[\begin{array}{cc}
\ce{O}\phantom{.......................}\\
||\phantom{.......................}\\
\phantom{}\ce{R - C - OH <-[H3O] Χ ->[H] RCH2NH2}
\end{array}\]


Which of the following amines can be prepared by Gabriel phthalimide reaction?


Identify the product ‘C’ in the following reaction.

\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]


Amides can be converted into amines by the reaction named ______.


Identify A and B in the following reaction.

\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]


Write a short note on the following:

Ammonolysis


Write a short note on the following:

Ammonolysis


Write a short note on Ammonolysis.


Write short note on the following.

Ammonolysis.


Write short notes on the following:

Ammonolysis 


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