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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Answer in one sentence. Which amide does produce ethanamine by Hofmann bromamide degradation reaction?

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प्रश्न

Answer in one sentence.

Which amide does produce ethanamine by Hofmann bromamide degradation reaction?

एका वाक्यात उत्तर
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उत्तर

Propanamide (C2H5CONH2) produces ethanamine by Hofmann bromamide degradation reaction.

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पाठ 13: Amines - Exercises [पृष्ठ २९७]

संबंधित प्रश्‍न

Write the chemical equation involved in the following reaction:

Hoffmann-bromamide degradation reaction


An aromatic compound 'A' of molecular formula C7H7ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions :


How do you convert the following: C6H5CONH2 to C6H5NH2


Give the structure of A, B and C in the following reaction:

\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]


Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]


Explain the mechanism of action of hydroiodic acid on 3-methylbutan-2-ol.


Mention 'two' uses of propan-2-one.


Give the structures of A, B and C in the following reactions :


Give the structures of A, B and C in the following reactions :


Choose the most correct option.

Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?


Answer the following

Write a reaction to convert acetic acid into methylamine.


Write reactions to prepare ethanamine from Acetonitrile.


Write the order of reactivity of alkyl halides with ammonia.


Write reactions to bring about the following conversions.

Acetamide to Ethylamine


Explain Hoffmann’s exhaustive alkylation with suitable reactions.


Explain the following reaction with a suitable example.

Hofmann elimination reaction


Acetamide on reduction using Na/C2H5OH gives ____________.


Identify the product 'A' in the following reaction.

\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]


Identify the major product (B).


What product is formed when \[\ce{R - C ≡ N}\] is hydrolysed?


What is the molar mass of the amine formed when acetamide undergoes Hofmann bromamide degradation?


Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?


For producing amines, the reaction of nitro compounds with iron scrap is preferred because:


Given below are two statements labelled as Assertion (A) and Reason (R).

Assertion (A): Alkyl halides are insoluble in water.

Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.

Select the most appropriate answer from the options given below:


Benzylamine may be alkylated as shown in the following equation:

\[\ce{C6H5CH2NH2 + R - X -> C6H5CH2NHR}\]

Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?


In order to prepare a 1° amine from an alkyl halide with simultaneous addition of one \[\ce{CH2}\] group in the carbon chain, the reagent used as source of nitrogen is ______.


Which of the following compounds is the weakest Brönsted base?


Among the following amines, the strongest Brönsted base is:


The reagents that can be used to convert benzenediazonium chloride to benzene are:

(i) \[\ce{SnCl2/HCl}\]

(ii) \[\ce{CH3CH2OH}\]

(iii) \[\ce{H3PO2}\]

(iv) \[\ce{LiAlH4}\]


Which of the following amines can be prepared by Gabriel synthesis.

(i) Isobutyl amine

(ii) 2-Phenylethylamine

(iii) N-methylbenzylamine

(iv) Aniline


Which of the following reactions are correct?

(i)

(ii)

(iii)

(iv)


Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?

(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].

(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].


Identify A and B in the following reaction.


Write following conversions:

acetanilide `->` p-nitroaniline


How will you carry out the following conversion?


How will you carry out the following conversions?


Assertion: Hoffmann’s bromamide reaction is given by primary amines.

Reason: Primary amines are more basic than secondary amines.


Describe Gabriel's phthalimide synthesis. (Give reaction)


The Gabriels' phthalimide synthesis is used in the synthesis of


Reduction of nitro alkanes yields which compound?


C6H5CONHCH3 can be converted into C6H5CH2NHCH3 by:-


Which of the following CANNOT be prepared by ammonolysis of alkyl halide?


Give reasons for the following:

Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.


Methyl amine on reaction with chloroform in the presence of NaOH gives ______.


  1. Phenyl methenamine
  2. N, N - Dimethylaniline
  3. N - Methyl aniline
  4. Benzenamine

Choose the correct order of the basic nature of the above amines.


Write the name of the product formed by the action of LiAlH4/ether on acetamide.


Which of the following would not be a good choice for reducing nitrobenzene to aniline?


Amides can be converted into amines by the reaction named ______.


Write short note on the following:

Ammonolysis


Write a short note on Ammonolysis.


Write short note on the following.

Ammonolysis.


Write a short note on Ammonolysis.


Write a short note on the following:

Ammonolysis.


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