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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

The following amines is the product of Gabriel phthalimide synthesis. - Chemistry

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प्रश्न

The following amines is the product of Gabriel phthalimide synthesis.

पर्याय

  • secondary aliphatic amine

  • primary aliphatic amine

  • aromatic primary amine

  • tertiary aliphatic amine

MCQ
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उत्तर

primary aliphatic amine

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
पाठ 13: Amines - Multiple Choice Questions

संबंधित प्रश्‍न

How are propan-1-amine and propan-2-amine prepared from oxime?


Identify the compounds 'A' and 'B' in the following equation:


Accomplish the following conversion:

Benzyl chloride to 2-phenylethanamine


Give the structure of A, B and C in the following reaction:

\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]


Give the structure of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]


Give the structures of A, B and C in the following reaction:

\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]


Give the structures of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}\]


Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?


Write the reaction of aromatic primary amine with nitrous acid.


Write the reaction of aliphatic primary amine with nitrous acid.


Give a plausible explanation for the following:

Why are amines less acidic than alcohols of comparable molecular masses?


Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :


Give the structures of A, B and C in the following reactions :


Give the structures of A, B and C in the following reactions :


 Write structures of compounds A and B in each of the following reactions:


Choose the most correct option.

Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?


Answer the following

Identify A and B in the following reactions.

\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]


Answer the following

Write a reaction to convert acetic acid into methylamine.


Answer the following

Explain Gabriel phthalimide synthesis.


Write reactions to bring about the following conversions.

Acetamide to methylamine


Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.


Identify compound 'B' in following series of reactions?

\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]


Identify the product 'A' in the following reaction.

\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]


Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.


\[\ce{CH3-CN ->[Na/C2H5OH]}\]

The product formed is ____________.


Which nitrogen containing compound amongst the following would undergo Mendius reduction to furnish primary amine \[\ce{(R - NH2)}\]?


Identify 'A' and 'B' in the following conversions.

\[\ce{CH3 - I ->[Alc. KCN][\Delta] A ->[Na/C2H5OH] B}\]


Identify the INCORRECT statement regarding Hofmann bromamide reaction.


Which of the following reagents is used in Mendius reduction reaction of alkyl cyanide?


Identify product B in the following reaction.

\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]


Which of the following reagents is used in Hofmann's elimination reaction of amines?


Which of the following reactions does NOT yield an amine?


Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:


Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.


The best reagent for converting 2–phenylpropanamide into 2-phenylpropanamine is ______.


The best reagent for converting, 2-phenylpropanamide into 1- phenylethanamine is ______.


Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?


What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?


What is the best reagent to convert nitrile to primary amine?


How will you carry out the following conversion?


How will you carry out the following conversions?


Match the reactions given in Column I with the statements given in Column II.

  Column I   Column II
(i) Ammonolysis (a) Amine with lesser number of carbon atoms
(ii) Gabriel phthalimide synthesis (b) Detection test for primary amines.
(iii) Hoffmann Bromamide reaction (c) Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\]
(iv) Carbylamine reaction (d) Reaction of alkylhalides with \[\ce{NH3}\]

Account for the following:

Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.


The Gabriels' phthalimide synthesis is used in the synthesis of


Ethylamine can be prepared by the action of bromine and caustic potash on which compound?


Give reasons for the following:

Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.


Methyl amine on reaction with chloroform in the presence of NaOH gives ______.


  1. Phenyl methenamine
  2. N, N - Dimethylaniline
  3. N - Methyl aniline
  4. Benzenamine

Choose the correct order of the basic nature of the above amines.


Which of the following statement(s) is/are incorrect in case of Hofmann bromamide degradation?


Write short note on the following:

Ammonolysis


Write short note on the following.

Ammonolysis.


Write a short note on the following:

Ammonolysis


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