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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

Identify 'A' and 'B' in the Following Reaction and Rewrite the Complete Reaction : - Chemistry

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प्रश्न

Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :

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उत्तर

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  या प्रश्नात किंवा उत्तरात काही त्रुटी आहे का?
2017-2018 (March)

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संबंधित प्रश्‍न

How are propan-1-amine and propan-2-amine prepared from oxime?


Write the chemical equation involved in the following reaction:

Hoffmann-bromamide degradation reaction


Give the structures of A, B and C in the following reactions :


Give the structure of A, B and C in the following reaction:

\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]


Give the structures of A, B and C in the following reaction:

\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]


Arrange the following in the increasing order of their pKvalues:

C6H5NH2, C2H5NH2, C6H5NHCH3


 Write structures of compounds A and B in each of the following reactions:


Answer in one sentence.

Predict the product of the following reaction.

\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]


Answer the following

Write a reaction to convert acetic acid into methylamine.


Mendius reaction is used to convert _____________


Write the order of reactivity of alkyl halides with ammonia.


Write reactions to bring about the following conversions.

Acetamide to methylamine


Explain Hoffmann’s exhaustive alkylation with suitable reactions.


Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.


Identify compound 'B' in following series of reactions?

\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]


Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.


The end product C of the following reaction is

\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]


Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.


Which of the following amines exhibits maximum degree of intermolecular hydrogen bonding?


Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?


Identify the product obtained when benzamide is treated with bromine and aqueous sodium hydroxide?


Identify product B in the following reaction.

\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]


Which of the following reagents is used in Hofmann's elimination reaction of amines?


Which of the following does NOT give carbylamine test?


Nitro compounds are reduced by iron scrap and hydrochloric acid to yield one of the following compounds:


The best reagent for converting, 2-phenylpropanamide into 1- phenylethanamine is ______.


Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.


Which of the following compounds is the weakest Brönsted base?


Which of the following amines can be prepared by Gabriel synthesis.

(i) Isobutyl amine

(ii) 2-Phenylethylamine

(iii) N-methylbenzylamine

(iv) Aniline


Which of the following reactions are correct?

(i)

(ii)

(iii)

(iv)


Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?

(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].

(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].

(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].


What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?


Suggest a route by which the following conversion can be accomplished.


How will you bring out the following conversion?


How will you carry out the following conversion?


How will you carry out the following conversions?


Assertion: Hoffmann’s bromamide reaction is given by primary amines.

Reason: Primary amines are more basic than secondary amines.


Account for the following:

Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.


The compound X is which of the following?

\[\ce{CH3CN ->[Na + C2H5OH] x}\]


Ethylamine can be prepared by the action of bromine and caustic potash on which compound?


Acetamide and ethyl amide can be distinguished by reacting with.


Give reasons for the following:

Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.


Methyl amine on reaction with chloroform in the presence of NaOH gives ______.


Which of the following amines can be prepared by Gabriel phthalimide reaction?


  1. Phenyl methenamine
  2. N, N - Dimethylaniline
  3. N - Methyl aniline
  4. Benzenamine

Choose the correct order of the basic nature of the above amines.


Which of the following statement(s) is/are incorrect in case of Hofmann bromamide degradation?


Amides can be converted into amines by the reaction named ______.


Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.


Write short note on the following:

Ammonolysis


Write short note on the following.

Ammonolysis.


Write short notes on the following:

Ammonolysis 


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