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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Give the structures of A, B and C in the following reaction: {CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C} - Chemistry

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प्रश्न

Give the structures of A, B and C in the following reaction:

\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]

रासायनिक समीकरणे/रचना
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उत्तर

\[\ce{\underset{Ethanoic acid}{CH3COOH} ->[NH3][\Delta] \underset{(A)}{\underset{Ethanamide}{CH3CONH2}} ->[NaOBr] \underset{(B)}{\underset{Methanamine}{CH3NH2}} ->[NaNO2/HCl] \underset{(C)}{\underset{Methanol}{CH3OH}}}\]

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पाठ 9: Amines - Exercises [पृष्ठ २७९]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 9 Amines
Exercises | Q 9.9 (v) | पृष्ठ २७९

संबंधित प्रश्‍न

Write a short note on Hoffmann bromamide degradation.


Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis


Accomplish the following conversion:

Nitrobenzene to benzoic acid


Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]


Write the reaction of aliphatic primary amine with nitrous acid.


Arrange the following in the increasing order of their pKvalues:

C6H5NH2, C2H5NH2, C6H5NHCH3


Give the structures of A, B and C in the following reactions :


 Write structures of compounds A and B in each of the following reactions:


Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?


Reduction of nitrobenzene by which of the following reagent gives aniline?

(i) \[\ce{Sn/HCl}\]

(ii) \[\ce{Fe/HCl}\]

(iii) \[\ce{H2 - Pd}\]

(iv) \[\ce{Sn/NH4OH}\]


Match the reactions given in Column I with the statements given in Column II.

  Column I   Column II
(i) Ammonolysis (a) Amine with lesser number of carbon atoms
(ii) Gabriel phthalimide synthesis (b) Detection test for primary amines.
(iii) Hoffmann Bromamide reaction (c) Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\]
(iv) Carbylamine reaction (d) Reaction of alkylhalides with \[\ce{NH3}\]

Account for the following:

Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.


When primary amines are treated with HCl, the product obtained is which of the following?


A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.


Amides can be converted into amines by the reaction named ______.


Write short note on the following:

Ammonolysis


Write a short note on Ammonolysis.


Write short notes on the following:

Ammonolysis 


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