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प्रश्न
Identify the compounds 'A' and 'B' in the following equation:
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उत्तर
A:CH3-CH2-NO2
(Nitro ethane)
B:CH3-CH2-NH2
(Ethanamine)
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संबंधित प्रश्न
How are propan-1-amine and propan-2-amine prepared from oxime?
Write the chemical equation involved in the following reaction:
Hoffmann-bromamide degradation reaction
Write a short note on the following:
Hoffmann’s bromamide reaction
Accomplish the following conversion:
Benzyl chloride to 2-phenylethanamine
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5N2Cl ->[CuCN] A ->[H2O/H+] B ->[NH3][\Delta] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]
Give the structures of A, B and C in the following reaction:
\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]
Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?
Explain the mechanism of action of hydroiodic acid on 3-methylbutan-2-ol.
Mention 'two' uses of propan-2-one.
Give the structures of A, B and C in the following reactions :
Answer in one sentence.
Predict the product of the following reaction.
\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]
Write the order of reactivity of alkyl halides with ammonia.
Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.
Identify compound 'B' in following series of reactions?
\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]
Identify the product 'A' in the following reaction.
\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]
The end product C of the following reaction is
\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]
What is the molar mass of the amine formed when acetamide undergoes Hofmann bromamide degradation?
\[\ce{CH3-CN ->[Na/C2H5OH]}\]
The product formed is ____________.
Which nitrogen containing compound amongst the following would undergo Mendius reduction to furnish primary amine \[\ce{(R - NH2)}\]?
Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?
The reduction of alkyl cyanide with sodium and ethanol to give primary amines is, ____________.
In aqueous phase the order of basic strength of alkylamine is ______.
Which of the following reagents is used in Hofmann's elimination reaction of amines?
Which of the following reactions does NOT yield an amine?
In order to prepare a 1° amine from an alkyl halide with simultaneous addition of one \[\ce{CH2}\] group in the carbon chain, the reagent used as source of nitrogen is ______.
Amongst the given set of reactants, the most appropriate for preparing 2° amine is ______.
Which of the following compounds is the weakest Brönsted base?
Reduction of nitrobenzene by which of the following reagent gives aniline?
(i) \[\ce{Sn/HCl}\]
(ii) \[\ce{Fe/HCl}\]
(iii) \[\ce{H2 - Pd}\]
(iv) \[\ce{Sn/NH4OH}\]
Which of the following reactions are correct?
(i)
(ii)
(iii)
(iv)
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
Identify A and B in the following reaction.
How will you bring out the following conversion?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Assertion: Hoffmann’s bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.
Describe Gabriel's phthalimide synthesis. (Give reaction)
Account for the following:
Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.
The compound X is which of the following?
\[\ce{CH3CN ->[Na + C2H5OH] x}\]
Ethylamine can be prepared by the action of bromine and caustic potash on which compound?
Reduction of nitro alkanes yields which compound?
Which of the following compound is expected to be most basic?
C6H5CONHCH3 can be converted into C6H5CH2NHCH3 by:-
Which of the following CANNOT be prepared by ammonolysis of alkyl halide?
Give reasons for the following:
Ammonolysis of alkyl halides is not a good method to prepare pure primary amines.
Which of the following compound gives pink colour on reaction with phthalic anhydride in cone. H2SO4 followed by treatment with NaOH?
Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?
Which of the following amines can be prepared by Gabriel phthalimide reaction?
The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is ______.
What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?
Write the name of the product formed by the action of LiAlH4/ether on acetamide.
Identify the compo ds A and B in the following reactions:
\[\ce{A ->[Nitrating mixture] B ->[(i) Sn/cone. HCI][(ii) NaOH] Aniline}\]
Write the name of reduction product formed when ethyl cyanide is treated with sodium and alcohol.
Write a short note on the following:
Ammonolysis.
