Advertisements
Advertisements
Question
Identify the compounds 'A' and 'B' in the following equation:
Advertisements
Solution
A:CH3-CH2-NO2
(Nitro ethane)
B:CH3-CH2-NH2
(Ethanamine)
APPEARS IN
RELATED QUESTIONS
How are propan-1-amine and propan-2-amine prepared from oxime?
Write a short note on Hoffmann bromamide degradation.
Write the chemical equation involved in the following reaction:
Hoffmann-bromamide degradation reaction
How do you convert the following: C6H5CONH2 to C6H5NH2
Write a short note on the following:
Hoffmann’s bromamide reaction
Accomplish the following conversion:
Nitrobenzene to benzoic acid
Give the structures of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[HNO2][273 K] B ->[C6H5OH] C}\]
Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?
Write the reaction of aromatic primary amine with nitrous acid.
Write the reaction of aliphatic primary amine with nitrous acid.
Mention 'two' uses of propan-2-one.
Answer the following
Explain the ammonolysis of alkyl halides.
Mendius reaction is used to convert _____________
Name the process of breaking C-X bond by ammonia in preparation of amines.
Write the order of reactivity of alkyl halides with ammonia.
Explain Hoffmann’s exhaustive alkylation with suitable reactions.
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Explain the following reaction with a suitable example.
Hofmann elimination reaction
Identify the product 'A' in the following reaction.
\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]
Identify the major product (B).
What product is formed when \[\ce{R - C ≡ N}\] is hydrolysed?
What is the molar mass of the amine formed when acetamide undergoes Hofmann bromamide degradation?
Which nitrogen containing compound amongst the following would undergo Mendius reduction to furnish primary amine \[\ce{(R - NH2)}\]?
Identify the product obtained when benzamide is treated with bromine and aqueous sodium hydroxide?
Identify 'A' and 'B' in the following conversions.
\[\ce{CH3 - I ->[Alc. KCN][\Delta] A ->[Na/C2H5OH] B}\]
Identify the INCORRECT statement regarding Hofmann bromamide reaction.
In aqueous phase the order of basic strength of alkylamine is ______.
Identify product B in the following reaction.
\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]
Which of the following reagents is used in Hofmann's elimination reaction of amines?
Which of the following does NOT give carbylamine test?
Which of the following reactions does NOT yield an amine?
Amongst the following, the strongest base in aqueous medium is ______.
Hoffmann Bromamide Degradation reaction is shown by ______.
The reagents that can be used to convert benzenediazonium chloride to benzene are:
(i) \[\ce{SnCl2/HCl}\]
(ii) \[\ce{CH3CH2OH}\]
(iii) \[\ce{H3PO2}\]
(iv) \[\ce{LiAlH4}\]
What is the best reagent to convert nitrile to primary amine?
Write following conversions:
nitrobenzene `->` acetanilide
How will you bring out the following conversion?
How will you carry out the following conversions?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
The Gabriels' phthalimide synthesis is used in the synthesis of
Reduction of nitro alkanes yields which compound?
Which of the following compound is expected to be most basic?
A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.
Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?
Which of the following amines can be prepared by Gabriel phthalimide reaction?
Write the name of the product formed by the action of LiAlH4/ether on acetamide.
Amides can be converted into amines by the reaction named ______.
Identify the compo ds A and B in the following reactions:
\[\ce{A ->[Nitrating mixture] B ->[(i) Sn/cone. HCI][(ii) NaOH] Aniline}\]
Identify A and B in the following reaction.
\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]
Write a short note on the following:
Ammonolysis
Write short note on the following:
Ammonolysis
Write a short note on Ammonolysis.
