English
Karnataka Board PUCPUC Science 2nd PUC Class 12

What is the best reagent to convert nitrile to primary amine?

Advertisements
Advertisements

Question

What is the best reagent to convert nitrile to primary amine?

Short/Brief Note
Advertisements

Solution

On treatment of nitriles with strong reducing agents such as lithium aluminium hydride in either of sodium metal in alcohol, primary amines are obtained.

\[\ce{\underset{Alkyl nitrile}{R - CN} + 4[H] ->[Na/C2H5OH][or LiAH4/ether]  R - Cl2NH2}\]

shaalaa.com
  Is there an error in this question or solution?
Chapter 13: Amines - Multiple Choice Questions (Type - I) [Page 189]

APPEARS IN

NCERT Exemplar Chemistry Exemplar [English] Class 12
Chapter 13 Amines
Multiple Choice Questions (Type - I) | Q 41 | Page 189

RELATED QUESTIONS

Give the structures of A, B and C in the following reactions :


Give the structures of A, B and C in the following reactions :


Write reactions to bring about the following conversions.

Acetamide to Ethylamine


Why cannot aniline be prepared by Gabriel phthalimide synthesis?


Explain the following reaction with a suitable example.

Hofmann elimination reaction


Identify the product 'A' in the following reaction.

\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]


Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.


The end product C of the following reaction is

\[\ce{C2H5NH2 ->[HNO2] A ->[PCl5] B ->[NH3][Alcohol] C}\]


Identify the product obtained when benzamide is treated with bromine and aqueous sodium hydroxide?


Quaternary ammonium salt is formed:


Given below are two statements labelled as Assertion (A) and Reason (R).

Assertion (A): Alkyl halides are insoluble in water.

Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.

Select the most appropriate answer from the options given below:


Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.


Which of the following compounds is the weakest Brönsted base?


How will you carry out the following conversions?


Describe Gabriel's phthalimide synthesis. (Give reaction)


A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.


Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?


Write a short note on Ammonolysis.


Write a short note on the following:

Ammonolysis.


Share
Notifications

Englishहिंदीमराठी


      Forgot password?
Use app×