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प्रश्न
What is the best reagent to convert nitrile to primary amine?
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उत्तर
On treatment of nitriles with strong reducing agents such as lithium aluminium hydride in either of sodium metal in alcohol, primary amines are obtained.
\[\ce{\underset{Alkyl nitrile}{R - CN} + 4[H] ->[Na/C2H5OH][or LiAH4/ether] R - Cl2NH2}\]
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संबंधित प्रश्न
How are propan-1-amine and propan-2-amine prepared from oxime?
Accomplish the following conversion:
Benzamide to toluene
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Give the structures of A, B and C in the following reaction:
\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]
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Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
Give the structures of A, B and C in the following reactions :
Choose the most correct option.
Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?
Explain the following reaction with a suitable example.
Hofmann elimination reaction
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nitrobenzene `->` acetanilide
How will you carry out the following conversion?
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When primary amines are treated with HCl, the product obtained is which of the following?
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Write short note on the following.
Ammonolysis.
