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प्रश्न
What is the best reagent to convert nitrile to primary amine?
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उत्तर
On treatment of nitriles with strong reducing agents such as lithium aluminium hydride in either of sodium metal in alcohol, primary amines are obtained.
\[\ce{\underset{Alkyl nitrile}{R - CN} + 4[H] ->[Na/C2H5OH][or LiAH4/ether] R - Cl2NH2}\]
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संबंधित प्रश्न
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Write the reaction of aliphatic primary amine with nitrous acid.
Give the structures of A, B and C in the following reactions :
Answer the following
Identify A and B in the following reactions.
\[\ce{C6H5CH2Br->[alco.][KCN]A ->[Na/ethanol]B.}\]
Answer the following
Explain Gabriel phthalimide synthesis.
The following amines is the product of Gabriel phthalimide synthesis.
Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.
Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.
For producing amines, the reaction of nitro compounds with iron scrap is preferred because:
Benzylamine may be alkylated as shown in the following equation:
\[\ce{C6H5CH2NH2 + R - X -> C6H5CH2NHR}\]
Which of the following alkylhalides is best suited for this reaction through SN1 mechanism?
Which of the following compounds is the weakest Brönsted base?
Which of the following reactions are correct?
(i)
(ii)
(iii)
(iv)
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Assertion: Hoffmann’s bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is ______.
Amides can be converted into amines by the reaction named ______.
Write a short note on Ammonolysis.
Write short note on the following:
Ammonolysis
