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प्रश्न
Write the reaction of aromatic primary amine with nitrous acid.
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उत्तर
Aromatic amine react with nitrous acid (prepared in situ from NaNO2 and a mineral acid such as HCl) at 273 − 278 K to form stable aromatic diazonium salts, i.e., NaCl and H2O.
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संबंधित प्रश्न
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Choose the most correct option.
Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?
Answer in one sentence.
Which amide does produce ethanamine by Hofmann bromamide degradation reaction?
Answer the following
Explain the ammonolysis of alkyl halides.
Write reactions to prepare ethanamine from Acetonitrile.
Acetamide on reduction using Na/C2H5OH gives ____________.
Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine?
Hoffmann Bromamide Degradation reaction is shown by ______.
The reagents that can be used to convert benzenediazonium chloride to benzene are:
(i) \[\ce{SnCl2/HCl}\]
(ii) \[\ce{CH3CH2OH}\]
(iii) \[\ce{H3PO2}\]
(iv) \[\ce{LiAlH4}\]
Write following conversions:
nitrobenzene `->` acetanilide
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
Assertion: Aromatic 1° amines can be prepared by Gabriel Phthalimide Synthesis.
Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.
Which of the following compound is expected to be most basic?
C6H5CONHCH3 can be converted into C6H5CH2NHCH3 by:-
Which of the following CANNOT be prepared by ammonolysis of alkyl halide?
Write the name of the product formed by the action of LiAlH4/ether on acetamide.
Identify the compo ds A and B in the following reactions:
\[\ce{A ->[Nitrating mixture] B ->[(i) Sn/cone. HCI][(ii) NaOH] Aniline}\]
Identify A and B in the following reaction.
\[\ce{C6H5CH2Br ->[Alco.][KCN] A ->[Na/Ethanol][reduction] B}\]
Write a short note on Ammonolysis.
Write a short note on Ammonolysis.
