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प्रश्न
Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is ______.
विकल्प
Hoffmann Bromamide reaction
Gabriel phthalimide synthesis
Sandmeyer reaction
Reaction with \[\ce{NH3}\]
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उत्तर
Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is Gabriel phthalimide synthesis.
Explanation:
Gabriel phthalimide synthesis is used to get primary amine from alkyl halide without any change in number of carbon atoms.
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संबंधित प्रश्न
An aromatic compound 'A' of molecular formula C7H7ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions :
Write the reaction of aliphatic primary amine with nitrous acid.
Mendius reaction is used to convert _____________
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
____________ can be prepared exclusively by Gabriel phthalimide synthesis.
Identify the INCORRECT statement regarding Hofmann bromamide reaction.
Which of the following compounds is obtained when quaternary ammonium hydroxide is strongly heated?
For producing amines, the reaction of nitro compounds with iron scrap is preferred because:
Quaternary ammonium salt is formed:
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
Write following conversions:
acetanilide `->` p-nitroaniline
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
Ethylamine can be prepared by the action of bromine and caustic potash on which compound?
Which of the following compound is expected to be most basic?
Which of the following CANNOT be prepared by ammonolysis of alkyl halide?
Which of the following compound gives pink colour on reaction with phthalic anhydride in cone. H2SO4 followed by treatment with NaOH?
- Phenyl methenamine
- N, N - Dimethylaniline
- N - Methyl aniline
- Benzenamine
Choose the correct order of the basic nature of the above amines.
What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?
Write short notes on the following:
Ammonolysis
