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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Assertion: Only a small amount of HCl is required in the reduction of nitro compounds with iron scrap and HCl in the presence of steam. Reason: FeClX2 formed gets hydrolysed to release HCl during the

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प्रश्न

Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.

Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.

विकल्प

  • Both assertion and reason are wrong.

  • Both assertion and reason are correct statements but reason is not correct explanation of assertion.

  • Assertion is correct statement but reason is wrong statement.

  • Both assertion and reason are correct statements and reason is correct explanation of assertion.

  • Assertion is wrong statement but reason is correct statement.

MCQ
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उत्तर

Both assertion and reason are correct statements and reason is correct explanation of assertion.

Explanation:

\[\ce{Fe + 2HCl ->FeCl2 + 2[H] FeCl2 + H2O(g) -> FeO + 2HCl}\]

The nascent hydrogen formed act as is reducing agent for the reduction of nitro compounds.

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अध्याय 13: Amines - Multiple Choice Questions (Type - I) [पृष्ठ १९२]

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एनसीईआरटी एक्झांप्लर Chemistry Exemplar [English] Class 12
अध्याय 13 Amines
Multiple Choice Questions (Type - I) | Q 72 | पृष्ठ १९२

संबंधित प्रश्न

Identify the compounds 'A' and 'B' in the following equation:


Write a short note on the following:

Hoffmann’s bromamide reaction


Give the structure of A, B and C in the following reaction:

\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]


Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?


Write the reaction of aliphatic primary amine with nitrous acid.


The following amines is the product of Gabriel phthalimide synthesis.


Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.


What is the molar mass of the amine formed when acetamide undergoes Hofmann bromamide degradation?


Identify the product obtained when benzamide is treated with bromine and aqueous sodium hydroxide?


The best reagent for converting, 2-phenylpropanamide into 1- phenylethanamine is ______.


Reduction of nitrobenzene by which of the following reagent gives aniline?

(i) \[\ce{Sn/HCl}\]

(ii) \[\ce{Fe/HCl}\]

(iii) \[\ce{H2 - Pd}\]

(iv) \[\ce{Sn/NH4OH}\]


How will you carry out the following conversions?


A primary amine is formed by an amide on treatment with bromine and alkali. The primary amine has


In the given reaction what is the X?

\[\begin{array}{cc}
\ce{O}\phantom{.......................}\\
||\phantom{.......................}\\
\phantom{}\ce{R - C - OH <-[H3O] Χ ->[H] RCH2NH2}
\end{array}\]


Acetamide and ethyl amide can be distinguished by reacting with.


A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.


Which of the following statement(s) is/are incorrect in case of Hofmann bromamide degradation?


Write a short note on the following:

Ammonolysis


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