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प्रश्न
Among the following amines, the strongest Brönsted base is:
विकल्प
\[\ce{NH3}\]
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उत्तर
Explanation:
Pyrrolidine is the strongest of two bases because the lone pair of nitrogen does not involve sin resonance and the presence of two alkyl basic compounds increases the basic strength among the given four compounds.
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संबंधित प्रश्न
Write a short note on the following:
Hoffmann’s bromamide reaction
Give the structures of A, B and C in the following reaction:
\[\ce{CH3COOH ->[NH3][\Delta] A ->[NaOBr] B ->[NaNO2/HCl] C}\]
Give a plausible explanation for the following:
Why are amines less acidic than alcohols of comparable molecular masses?
Identify 'A' and 'B' in the following reaction and rewrite the complete reaction :
Give the structures of A, B and C in the following reactions :
Give the structures of A, B and C in the following reactions :
Account for the following:
Gabriel phthalimide synthesis is not preferred for preparing aromatic primary amines.
Write reactions to bring about the following conversions.
Acetamide to methylamine
Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.
What product is formed when \[\ce{R - C ≡ N}\] is hydrolysed?
Best method for preparing primary amines from alkyl halides without changing the number of carbon atoms in the chain is ______.
Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?
(i) Acetyl chloride/pyridine followed by reaction with conc.\[\ce{H2SO4 }\] + conc. \[\ce{HNO3}\].
(ii) Acetic anyhdride/pyridine followed by conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iii) Dil. HCl followed by reaction with conc.\[\ce{H2SO4}\] + conc.\[\ce{HNO3}\].
(iv) Reaction with conc.\[\ce{HNO3}\] + conc.\[\ce{H2 SO4}\].
How will you carry out the following conversion?
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
Describe Gabriel's phthalimide synthesis. (Give reaction)
Methyl amine on reaction with chloroform in the presence of NaOH gives ______.
Which of the following amines can be prepared by Gabriel phthalimide reaction?
Which of the following would not be a good choice for reducing nitrobenzene to aniline?
Write a short note on the following:
Ammonolysis
