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प्रश्न
Which of the following amines can be prepared by Gabriel synthesis.
(i) Isobutyl amine
(ii) 2-Phenylethylamine
(iii) N-methylbenzylamine
(iv) Aniline
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उत्तर
(i) Isobutyl amine
(ii) 2-Phenylethylamine
Explanation:
Gabriel synthesis is a method for producing primary amines. When phthalimide is treated with ethanolic potassium hydroxide, it forms a potassium salt of phthalimide, which when heated with an alkyl halide and then alkaline hydrolyzed yields the corresponding primary amine.
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संबंधित प्रश्न
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Identify the compounds 'A' and 'B' in the following equation:
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\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]
Give a plausible explanation for the following:
Why are amines less acidic than alcohols of comparable molecular masses?
Write reactions to bring about the following conversions.
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\[\ce{CH3-CN ->[Na/C2H5OH]}\]
The product formed is ____________.
In aqueous phase the order of basic strength of alkylamine is ______.
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\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]
Which of the following compounds is the weakest Brönsted base?
Identify A and B in the following reaction.
How will you bring out the following conversion?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
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Reason: Primary amines are more basic than secondary amines.
Assertion: Aromatic 1° amines can be prepared by Gabriel Phthalimide Synthesis.
Reason: Aryl halides undergo nucleophilic substitution with anion formed by phthalimide.
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Acetamide and ethyl amide can be distinguished by reacting with.
