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प्रश्न
Write reactions for the preparation of ethanamine using Gabriel phthalimide synthesis.
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उत्तर
Gabriel phthalimide synthesis for ethanamine:
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संबंधित प्रश्न
Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis
An aromatic compound 'A' of molecular formula C7H7ON undergoes a series of reactions as shown below. Write the structures of A, B, C, D and E in the following reactions :
How do you convert the following: C6H5CONH2 to C6H5NH2
How do you convert the following: Ethanenitrile to ethanamine
Accomplish the following conversion:
Nitrobenzene to benzoic acid
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2 + HCl][273 K] B ->[H2O/H+][\Delta] C}\]
Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?
Write the reaction of aliphatic primary amine with nitrous acid.
Mention 'two' uses of propan-2-one.
Answer in one sentence.
Which amide does produce ethanamine by Hofmann bromamide degradation reaction?
Answer the following
Write a reaction to convert acetic acid into methylamine.
Mendius reaction is used to convert _____________
Name the process of breaking C-X bond by ammonia in preparation of amines.
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Identify compound 'B' in following series of reactions?
\[\ce{Acetonitrile ->[Na/alcohol] A ->[NaNO2/dil.HCI] B}\]
Acetamide on reduction using Na/C2H5OH gives ____________.
Identify the product 'A' in the following reaction.
\[\ce{Aniline ->[(CH3CO)2O][Pyridine] A}\]
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
Identify the major product (B).
Which of the following amines forms a clear solution when treated with benzene sulphonyl chloride and excess of potassium hydroxide?
Identify the product obtained when benzamide is treated with bromine and aqueous sodium hydroxide?
Which of the following amines cannot be prepared by Gabriel phthalimide synthesis?
Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): Alkyl halides are insoluble in water.
Reason (R): Alkyl halides have halogen attached to sp3 hybrid carbon.
Select the most appropriate answer from the options given below:
Amongst the following, the strongest base in aqueous medium is ______.
Which of the following reagents would not be a good choice for reducing an aryl nitro compound to an amine?
Hoffmann Bromamide Degradation reaction is shown by ______.
Reduction of aromatic nitro compounds using \[\ce{Fe}\] and \[\ce{HCl}\] gives ______.
What is the product when \[\ce{C6H5CH2NH2}\] reacts with \[\ce{HNO2}\]?
What is the best reagent to convert nitrile to primary amine?
Suggest a route by which the following conversion can be accomplished.
Write following conversions:
nitrobenzene `->` acetanilide
How will you bring out the following conversion?
How will you carry out the following conversion?
How will you carry out the following conversions?
How will you carry out the following conversions?
Assertion: Only a small amount of \[\ce{HCl}\] is required in the reduction of nitro compounds with iron scrap and \[\ce{HCl}\] in the presence of steam.
Reason: \[\ce{FeCl2}\] formed gets hydrolysed to release \[\ce{HCl}\] during the reaction.
Describe Gabriel's phthalimide synthesis. (Give reaction)
Account for the following:
Aniline cannot be prepared by the ammonolysis of chlorobenzene under normal conditions.
The compound X is which of the following?
\[\ce{CH3CN ->[Na + C2H5OH] x}\]
Acetamide and ethyl amide can be distinguished by reacting with.
Which of the following compound is expected to be most basic?
A compound 'A' on reduction with iron scrap and hydrochloric acid gives compound 'B' with molecular formula C6H7N. Compound 'B' on reaction with CHCl3 and alcoholic KOH produces an obnoxious smell of carbylamine due to the formation of 'C'. Identify 'A', 'B' and 'C' and write the chemical reactions involved.
Methyl amine on reaction with chloroform in the presence of NaOH gives ______.
The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is ______.
Identify the product ‘C’ in the following reaction.
\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]
Write the name of the product formed by the action of LiAlH4/ether on acetamide.
Which of the following would not be a good choice for reducing nitrobenzene to aniline?
Identify the compo ds A and B in the following reactions:
\[\ce{A ->[Nitrating mixture] B ->[(i) Sn/cone. HCI][(ii) NaOH] Aniline}\]
Write short note on the following:
Ammonolysis
Write a short note on Ammonolysis.
Write short note on the following.
Ammonolysis.
Write a short note on Ammonolysis.
Write a short note on the following:
Ammonolysis
