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How are amines classified depending on the functional group? Give one example of each class of amines.

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प्रश्न

How are amines classified depending on the functional group? Give one example of each class of amines.

संक्षेप में उत्तर
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उत्तर

Classification of amines:

  1. Amines are classified as primary (1°), secondary (2°) and tertiary (3°) amines.
  2. Their structures are obtained in a simple way by replacing one, two, or three hydrogen atoms of NH3 molecule by alkyl/aryl groups.
  3. The functional group present in primary amines is referred to as an amino group (–NH2).
    e.g. Ethylamine [C2H5 – NH2]
  4. The functional group present in secondary amines is referred to as the imino group (>NH).
    e.g. Dimethylamine [(CH3)2NH]
  5. The functional group present in tertiary amines is tertiary nitrogen represented as:

    e.g. Trimethylamine [(CH3)3N]
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अध्याय 13: Amines - Short answer questions (Type-II)

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संबंधित प्रश्न

Classify the following amine as primary, secondary or tertiary:

(C2H5)2NH


In the following 

The compound ‘B’ is _______.
(A) Propan–1–amine

(B) Propan–2–amine

(C) Isopropylamine

(D) Dimethylamine


Choose the most correct option.

Which type of amine does produce N2 when treated with HNO2?


Choose the most correct option.

Carbylamine test is given by ____________.


Choose the most correct option.

Identify ‘B’ in the following reactions

\[\ce{CH3 - C ≡ N ->[Na/C2H5OH] A ->[NaNO2/dilHCl]B}\]


A tertiary amine is an organic compound ____________.


Which of the following amines is most basic in nature in aqueous phase?


\[\ce{Aniline + benzoylchloride ->[NaOH] C6H5 - NH - COC6H5}\] this reaction is known as ____________.


The product formed by the reaction an aldehyde with a primary amine ____________.


The order of basic strength for methyl substituted amines in aqueous solution is ____________.


Which of the following amines does not undergo acetylation?


Which one of the following is most basic?


IUPAC name for the amine is:

\[\begin{array}{cc}
\phantom{.}\ce{CH3}\\
|\phantom{..}\\
\ce{CH3 - N - C - CH2 - CH3}\\
\phantom{.}|\phantom{.....}|\phantom{........}\\
\phantom{}\ce{CH3}\phantom{..}\ce{C2H5}\phantom{....}
\end{array}\]


How will you convert nitrobenzene into m-nitro aniline?


Write a short note on the following.

Ammonolysis


Write a short note on the following.

Schotten-Baumann reaction


Write a short note on the following.

Mustard oil reaction


Account for the following.

Gabriel phthalimide synthesis is preferred for synthesising primary amines.


Account for the following.

Ethylamine is soluble in water whereas aniline is not.


Arrange the following:

In increasing order of solubility in water:

C6H5NH2, (C2H5)2NH, C2H5NH2


Arrange the following.

In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.


Arrange the following.

Increasing order of basic strength C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2.


Arrange the following.

In decreasing order of basic strength


How will you prepare propan-1-amine from 1-nitropropane?


Identify A, B and C.

\[\ce{CH3 - NO2 ->[LiAlH4] A ->[2CH3CH2Br] B ->[H2SO4] C}\]


How will you convert diethylamine into N, N-diethyl acetamide?


How will you convert diethylamine into N-nitrosodiethylamine?


The following amine can be classified as:


The main product is formed by treating an alkyl or benzyl halide with excess ammonia ____________.


Complete the following reaction.


The amine formed from an amide by mean of bromine and alkali has how many number of carbon atoms?


The reaction of NHO2 with 'A' gives quartering ammonium salt. A is which of the following?


\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{H - \underset{(A)}{C} - NH - CH3}
\end{array}\]

and 

\[\begin{array}{cc}
\ce{O}\\
||\\
\ce{CH3 - \underset{(B)}{C} - NH2}
\end{array}\]

are which type of isomers?


Classify the following amine as primary, secondary or tertiary:


Classify the following amine as primary, secondary or tertiary:

(C2H5)2CHNH2


Which among the following is the strongest Bronsted base?


Write short note on the following:

Ammonolysis


Write short notes on the following

Ammonolysis


Name the distinguishing test for differentiating 1° amine from 2° and 3° amine.


Define Amines.


Write a short note on the following

Ammonolysis


Account for the following:

Aniline does not undergo Friedel-Crafts reaction.


Write short note on Ammonolysis.


Write short note on the following:

Ammonolysis


Write a short note on the following.

Ammonolysis


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