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How are amines classified depending on the functional group? Give one example of each class of amines.

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प्रश्न

How are amines classified depending on the functional group? Give one example of each class of amines.

संक्षेप में उत्तर
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उत्तर

Classification of amines:

  1. Amines are classified as primary (1°), secondary (2°) and tertiary (3°) amines.
  2. Their structures are obtained in a simple way by replacing one, two, or three hydrogen atoms of NH3 molecule by alkyl/aryl groups.
  3. The functional group present in primary amines is referred to as an amino group (–NH2).
    e.g. Ethylamine [C2H5 – NH2]
  4. The functional group present in secondary amines is referred to as the imino group (>NH).
    e.g. Dimethylamine [(CH3)2NH]
  5. The functional group present in tertiary amines is tertiary nitrogen represented as:

    e.g. Trimethylamine [(CH3)3N]
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अध्याय 13: Amines - Short answer questions (Type-II)

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संबंधित प्रश्न

Classify the following amine as primary, secondary or tertiary:

(C2H5)2NH


In the following 

The compound ‘B’ is _______.
(A) Propan–1–amine

(B) Propan–2–amine

(C) Isopropylamine

(D) Dimethylamine


Isobutylamine is an example of ______.


Choose the most correct option.

Which type of amine does produce N2 when treated with HNO2?


Choose the most correct option.

Carbylamine test is given by ____________.


Choose the most correct option.

Identify ‘B’ in the following reactions

\[\ce{CH3 - C ≡ N ->[Na/C2H5OH] A ->[NaNO2/dilHCl]B}\]


What are amines?


How are amines classified?


What is the action of nitrous acid on the following compounds?

Isopropyl amine


Which of the following amines is most basic in nature in aqueous phase?


Assertion: Acetamide on reaction with KOH and bromine gives acetic acid.

Reason: Bromine catalyses hydrolysis of acetamide.


The order of basic strength for methyl substituted amines in aqueous solution is ____________.


\[\ce{C6H5NO2 ->[Fe/HCl] A ->[NaNO2/HCl][273 K] B ->[H2O][283 K] C}\] ‘C’ is:


Which of the following amines does not undergo acetylation?


Which one of the following is most basic?


IUPAC name for the amine is:

\[\begin{array}{cc}
\phantom{.}\ce{CH3}\\
|\phantom{..}\\
\ce{CH3 - N - C - CH2 - CH3}\\
\phantom{.}|\phantom{.....}|\phantom{........}\\
\phantom{}\ce{CH3}\phantom{..}\ce{C2H5}\phantom{....}
\end{array}\]


How will you convert nitrobenzene into m-nitro aniline?


Write a short note on the following:

Gabriel phthalimide synthesis


Write a short note on the following.

Schotten-Baumann reaction


Write a short note on the following.

Mustard oil reaction


Account for the following.

pKb of aniline is more than that of methylamine.


Account for the following.

Ethylamine is soluble in water whereas aniline is not.


Account for the following.

Although amino group is o- and p-directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.


Arrange the following.

In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.


Arrange the following.

In decreasing order of the pKb values C2H5NH2, C6H5NHCH3, (C2H)2NH and CH3NH2.


Arrange the following.

Increasing order of basic strength C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2.


How will you prepare propan-1-amine from butane nitrile?


Identify A, B and C.

\[\ce{CH3 - NO2 ->[LiAlH4] A ->[2CH3CH2Br] B ->[H2SO4] C}\]


(C2H5)2CHNH2. The following amine can be classified as:


The following amine can be classified as:


The main product is formed by treating an alkyl or benzyl halide with excess ammonia ____________.


Complete the following reaction.


\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{H - \underset{(A)}{C} - NH - CH3}
\end{array}\]

and 

\[\begin{array}{cc}
\ce{O}\\
||\\
\ce{CH3 - \underset{(B)}{C} - NH2}
\end{array}\]

are which type of isomers?


Classify the following amine as primary, secondary or tertiary:


Among the following, which is the strongest base?


Arrange the increasing order of solubility in water.

\[\ce{C2H5Cl, C2H5NH2, C2H5OH}\]


Write short note on the following:

Ammonolysis


Write a short note on the following.

Ammonolysis


Name the distinguishing test for differentiating 1° amine from 2° and 3° amine.


Write short note on the following.

Ammonolysis


Write a short note on the following

Ammonolysis


Write a short note on the following.

Ammonolysis


Write short note on the following.

Ammonolysis


Write short note on Ammonolysis.


Write a short note on the following.

Ammonolysis


Write a short note on the following.

Ammonolysis


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