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Question
How are amines classified depending on the functional group? Give one example of each class of amines.
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Solution
Classification of amines:
- Amines are classified as primary (1°), secondary (2°) and tertiary (3°) amines.
- Their structures are obtained in a simple way by replacing one, two, or three hydrogen atoms of NH3 molecule by alkyl/aryl groups.
- The functional group present in primary amines is referred to as an amino group (–NH2).
e.g. Ethylamine [C2H5 – NH2] - The functional group present in secondary amines is referred to as the imino group (>NH).
e.g. Dimethylamine [(CH3)2NH] - The functional group present in tertiary amines is tertiary nitrogen represented as:

e.g. Trimethylamine [(CH3)3N]
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RELATED QUESTIONS
In the following

The compound ‘B’ is _______.
(A) Propan–1–amine
(B) Propan–2–amine
(C) Isopropylamine
(D) Dimethylamine
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Isobutylamine is an example of ______.
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\[\ce{Aniline + benzoylchloride ->[NaOH] C6H5 - NH - COC6H5}\] this reaction is known as ____________.
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Which one of the following is most basic?
IUPAC name for the amine is:
\[\begin{array}{cc}
\phantom{.}\ce{CH3}\\
|\phantom{..}\\
\ce{CH3 - N - C - CH2 - CH3}\\
\phantom{.}|\phantom{.....}|\phantom{........}\\
\phantom{}\ce{CH3}\phantom{..}\ce{C2H5}\phantom{....}
\end{array}\]
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Gabriel phthalimide synthesis
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Schotten-Baumann reaction
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Carbylamine reaction
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Mustard oil reaction
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Account for the following.
pKb of aniline is more than that of methylamine.
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Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Arrange the following.
In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.
Arrange the following.
Increasing order of basic strength C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2.
How will you prepare propan-1-amine from butane nitrile?
How will you prepare propan-1-amine from propanamide?
How will you prepare propan-1-amine from 1-nitropropane?
Identify A, B and C.
\[\ce{CH3 - NO2 ->[LiAlH4] A ->[2CH3CH2Br] B ->[H2SO4] C}\]
(C2H5)2CHNH2. The following amine can be classified as:
The following amine can be classified as (C2H5)2NH:
The main product is formed by treating an alkyl or benzyl halide with excess ammonia ____________.
Complete the following reaction.

The amine formed from an amide by mean of bromine and alkali has how many number of carbon atoms?
\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{H - \underset{(A)}{C} - NH - CH3}
\end{array}\]
and
\[\begin{array}{cc}
\ce{O}\\
||\\
\ce{CH3 - \underset{(B)}{C} - NH2}
\end{array}\]
are which type of isomers?
Classify the following amine as primary, secondary or tertiary:

Classify the following amine as primary, secondary or tertiary:

Assertion A: Aniline on nitration yields ortho, meta and para nitro derivatives of aniline.
Reason R: Nitrating mixture is a storng acidic mixture.
In the light of the above statements, choose the correct answer from the options given below:
Among the following, which is the strongest base?
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Ammonolysis
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Ammonolysis
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Ammonolysis
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Ammonolysis
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Ammonolysis
Write short note on the following.
Ammonolysis
Write a short note on the following.
Ammonolysis
Write a short note on the following.
Ammonolysis
