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प्रश्न
How are amines classified depending on the functional group? Give one example of each class of amines.
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उत्तर
Classification of amines:
- Amines are classified as primary (1°), secondary (2°) and tertiary (3°) amines.
- Their structures are obtained in a simple way by replacing one, two, or three hydrogen atoms of NH3 molecule by alkyl/aryl groups.
- The functional group present in primary amines is referred to as an amino group (–NH2).
e.g. Ethylamine [C2H5 – NH2] - The functional group present in secondary amines is referred to as the imino group (>NH).
e.g. Dimethylamine [(CH3)2NH] - The functional group present in tertiary amines is tertiary nitrogen represented as:
e.g. Trimethylamine [(CH3)3N]
APPEARS IN
संबंधित प्रश्न
Classify the following amine as primary, secondary or tertiary:
(C2H5)2NH
Isobutylamine is an example of ______.
Choose the most correct option.
Which type of amine does produce N2 when treated with HNO2?
Choose the most correct option.
Carbylamine test is given by ____________.
Choose the most correct option.
Identify ‘B’ in the following reactions
\[\ce{CH3 - C ≡ N ->[Na/C2H5OH] A ->[NaNO2/dilHCl]B}\]
What are amines?
How are amines classified?
Write the number of moles of ethanoyl chloride required for complete acylation of N, N-dimethylaniline.
What is the action of nitrous acid on the following compounds?
Isopropyl amine
A tertiary amine is an organic compound ____________.
Which of the following amines is most basic in nature in aqueous phase?
Assertion: Acetamide on reaction with KOH and bromine gives acetic acid.
Reason: Bromine catalyses hydrolysis of acetamide.
\[\ce{Aniline + benzoylchloride ->[NaOH] C6H5 - NH - COC6H5}\] this reaction is known as ____________.
When aniline reacts with acetic anhydride the product formed is ____________.
Which of the following amines does not undergo acetylation?
Which one of the following is most basic?
IUPAC name for the amine is:
\[\begin{array}{cc}
\phantom{.}\ce{CH3}\\
|\phantom{..}\\
\ce{CH3 - N - C - CH2 - CH3}\\
\phantom{.}|\phantom{.....}|\phantom{........}\\
\phantom{}\ce{CH3}\phantom{..}\ce{C2H5}\phantom{....}
\end{array}\]
How will you convert nitrobenzene into m-nitro aniline?
Write a short note on the following.
Ammonolysis
Write a short note on the following.
Carbylamine reaction
Write a short note on the following.
Mustard oil reaction
How will you distinguish between primary secondary and tertiary aliphatic amines?
Account for the following.
Ethylamine is soluble in water whereas aniline is not.
Account for the following.
Although amino group is o- and p-directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
Arrange the following:
In increasing order of solubility in water:
C6H5NH2, (C2H5)2NH, C2H5NH2
Arrange the following.
In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.
How will you prepare propan-1-amine from butane nitrile?
Identify A, B and C.
\[\ce{CH3 - NO2 ->[LiAlH4] A ->[2CH3CH2Br] B ->[H2SO4] C}\]
How will you convert diethylamine into N-nitrosodiethylamine?
(C2H5)2CHNH2. The following amine can be classified as:
The following amine can be classified as (C2H5)2NH:
Arrange the following in the increasing order of their basic strength:
C2H5NH2, C6H5NH2, (C2H5)2NH
Complete the following reaction.
The reaction of NHO2 with 'A' gives quartering ammonium salt. A is which of the following?
\[\begin{array}{cc}
\ce{O}\phantom{.........}\\
||\phantom{.........}\\
\ce{H - \underset{(A)}{C} - NH - CH3}
\end{array}\]
and
\[\begin{array}{cc}
\ce{O}\\
||\\
\ce{CH3 - \underset{(B)}{C} - NH2}
\end{array}\]
are which type of isomers?
Classify the following amine as primary, secondary or tertiary:
Assertion A: Aniline on nitration yields ortho, meta and para nitro derivatives of aniline.
Reason R: Nitrating mixture is a storng acidic mixture.
In the light of the above statements, choose the correct answer from the options given below:
Among the following, which is the strongest base?
Write short note on the following:
Ammonolysis
Write short notes on the following
Ammonolysis
Write a short note on the following.
Ammonolysis
Write a short note on the following
Ammonolysis
Write short note on Ammonolysis.
Write short note on the following:
Ammonolysis
