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महाराष्ट्र राज्य शिक्षण मंडळएचएससी विज्ञान (सामान्य) इयत्ता १२ वी

How are amines classified depending on the functional group? Give one example of each class of amines. - Chemistry

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प्रश्न

How are amines classified depending on the functional group? Give one example of each class of amines.

थोडक्यात उत्तर
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उत्तर

Classification of amines:

  1. Amines are classified as primary (1°), secondary (2°) and tertiary (3°) amines.
  2. Their structures are obtained in a simple way by replacing one, two, or three hydrogen atoms of NH3 molecule by alkyl/aryl groups.
  3. The functional group present in primary amines is referred to as an amino group (–NH2).
    e.g. Ethylamine [C2H5 – NH2]
  4. The functional group present in secondary amines is referred to as the imino group (>NH).
    e.g. Dimethylamine [(CH3)2NH]
  5. The functional group present in tertiary amines is tertiary nitrogen represented as:

    e.g. Trimethylamine [(CH3)3N]
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पाठ 13: Amines - Short answer questions (Type-II)

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संबंधित प्रश्‍न

Classify the following amine as primary, secondary or tertiary:

(C2H5)2NH


Give reasons for the following:

CH3NH2 is more basis than C6H5NH2.


Choose the most correct option.

The hybridisation of nitrogen in primary amine is ____________.


Choose the most correct option.

Which type of amine does produce N2 when treated with HNO2?


Choose the most correct option.

Identify ‘B’ in the following reactions

\[\ce{CH3 - C ≡ N ->[Na/C2H5OH] A ->[NaNO2/dilHCl]B}\]


What are amines?


How are amines classified?


Write the number of moles of ethanoyl chloride required for complete acylation of N, N-dimethylaniline.


Assertion: Acetamide on reaction with KOH and bromine gives acetic acid.

Reason: Bromine catalyses hydrolysis of acetamide.


The product formed by the reaction an aldehyde with a primary amine ____________.


Which one of the following is most basic?


IUPAC name for the amine is:

\[\begin{array}{cc}
\phantom{.}\ce{CH3}\\
|\phantom{..}\\
\ce{CH3 - N - C - CH2 - CH3}\\
\phantom{.}|\phantom{.....}|\phantom{........}\\
\phantom{}\ce{CH3}\phantom{..}\ce{C2H5}\phantom{....}
\end{array}\]


How will you convert nitrobenzene into m-nitro aniline?


Write a short note on the following.

Carbylamine reaction


Write a short note on the following.

Mustard oil reaction


How will you distinguish between primary secondary and tertiary aliphatic amines?


Account for the following.

pKb of aniline is more than that of methylamine.


Account for the following.

Although amino group is o- and p-directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.


Arrange the following:

In increasing order of solubility in water:

C6H5NH2, (C2H5)2NH, C2H5NH2


Arrange the following.

In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.


Arrange the following.

In decreasing order of the pKb values C2H5NH2, C6H5NHCH3, (C2H)2NH and CH3NH2.


Arrange the following.

Increasing order of basic strength C6H5NH2, C6H5N(CH3)2, (C2H5)2NH and CH3NH2.


How will you prepare propan-1-amine from 1-nitropropane?


How will you convert diethylamine into N, N-diethyl acetamide?


How will you convert diethylamine into N-nitrosodiethylamine?


(C2H5)2CHNH2. The following amine can be classified as:


The following amine can be classified as (C2H5)2NH:


The following amine can be classified as:


Classify the following amine as primary, secondary or tertiary:


Classify the following amine as primary, secondary or tertiary:


Classify the following amine as primary, secondary or tertiary:

(C2H5)2CHNH2


Which among the following is the strongest Bronsted base?


Assertion A: Aniline on nitration yields ortho, meta and para nitro derivatives of aniline.

Reason R: Nitrating mixture is a storng acidic mixture.
In the light of the above statements, choose the correct answer from the options given below: 


Among the following, which is the strongest base?


Arrange the increasing order of solubility in water.

\[\ce{C2H5Cl, C2H5NH2, C2H5OH}\]


Write short notes on the following

Ammonolysis


Write a short note on the following.

Ammonolysis


Name the distinguishing test for differentiating 1° amine from 2° and 3° amine.


Write a short note on the following

Ammonolysis


Write a short note on the following.

Ammonolysis


Account for the following:

Aniline does not undergo Friedel-Crafts reaction.


Write a short note on the following.

Ammonolysis


Write a short note on the following.

Ammonolysis


Write a short note on the following.

Ammonolysis


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