Advertisements
Advertisements
प्रश्न
Write a short note on the following:
Gabriel phthalimide synthesis
Advertisements
उत्तर
Gabriel synthesis is used for the preparation of primary amines. Phthalimide, on treatment with ethanolic potassium hydroxide, forms potassium salt of phthalimide, which on heating with alkyl halide followed by alkaline hydrolysis, produces the corresponding primary amine. Aromatic primary amines cannot be prepared by this method because aryl halides do not undergo nucleophilic substitution with the anion formed by phthalimide.
संबंधित प्रश्न
Choose the most correct option.
The hybridisation of nitrogen in primary amine is ____________.
What is the action of nitrous acid on the following compounds?
Isopropyl amine
A tertiary amine is an organic compound ____________.
When aniline reacts with acetic anhydride the product formed is ____________.
How will you convert nitrobenzene into m-nitro aniline?
Write a short note on the following.
Ammonolysis
Write a short note on the following.
Carbylamine reaction
Write a short note on the following.
Mustard oil reaction
How will you distinguish between primary secondary and tertiary aliphatic amines?
Account for the following.
Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Account for the following.
Ethylamine is soluble in water whereas aniline is not.
Account for the following.
Although amino group is o- and p-directing in aromatic electrophilic substitution reactions, aniline on nitration gives a substantial amount of m-nitroaniline.
Arrange the following.
In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.
Arrange the following.
In decreasing order of basic strength
How will you convert diethylamine into N, N-diethyl acetamide?
How will you convert diethylamine into N-nitrosodiethylamine?
The reaction of NHO2 with 'A' gives quartering ammonium salt. A is which of the following?
Classify the following amine as primary, secondary or tertiary:
Classify the following amine as primary, secondary or tertiary:
Assertion A: Aniline on nitration yields ortho, meta and para nitro derivatives of aniline.
Reason R: Nitrating mixture is a storng acidic mixture.
In the light of the above statements, choose the correct answer from the options given below:
Arrange the increasing order of solubility in water.
\[\ce{C2H5Cl, C2H5NH2, C2H5OH}\]
Write short note on the following:
Ammonolysis
Write short notes on the following
Ammonolysis
Name the distinguishing test for differentiating 1° amine from 2° and 3° amine.
Write a short note on the following.
Ammonolysis
