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प्रश्न
Write a short note on the following:
Gabriel phthalimide synthesis
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उत्तर
Gabriel synthesis is used for the preparation of primary amines. Phthalimide, on treatment with ethanolic potassium hydroxide, forms potassium salt of phthalimide, which on heating with alkyl halide followed by alkaline hydrolysis, produces the corresponding primary amine. Aromatic primary amines cannot be prepared by this method because aryl halides do not undergo nucleophilic substitution with the anion formed by phthalimide.
संबंधित प्रश्न
Choose the most correct option.
The hybridisation of nitrogen in primary amine is ____________.
Isobutylamine is an example of ______.
Choose the most correct option.
Which type of amine does produce N2 when treated with HNO2?
Choose the most correct option.
Carbylamine test is given by ____________.
A tertiary amine is an organic compound ____________.
Which of the following amines is most basic in nature in aqueous phase?
\[\ce{Aniline + benzoylchloride ->[NaOH] C6H5 - NH - COC6H5}\] this reaction is known as ____________.
Which of the following amines does not undergo acetylation?
Which one of the following is most basic?
How will you convert nitrobenzene into m-nitro aniline?
Write a short note on the following.
Schotten-Baumann reaction
Write a short note on the following.
Mustard oil reaction
Account for the following.
Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Arrange the following.
In decreasing order of basic strength in gas phase (C2H5)NH2, (C2H5)NH, (C2H5)3N and NH3.
Arrange the following.
In increasing order of boiling point C6H5OH, (CH3)2NH, C2H5NH2.
How will you convert diethylamine into N, N-diethyl acetamide?
How will you convert diethylamine into N-nitrosodiethylamine?
(C2H5)2CHNH2. The following amine can be classified as:
The following amine can be classified as:
Classify the following amine as primary, secondary or tertiary:
Among the following, which is the strongest base?
Write short notes on the following
Ammonolysis
Write short note on the following.
Ammonolysis
Define Amines.
Account for the following:
Aniline does not undergo Friedel-Crafts reaction.
Write a short note on the following.
Ammonolysis
