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प्रश्न
Answer the following
Write a reaction to convert acetic acid into methylamine.
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उत्तर
\[\ce{\underset{Ethanoic acid}{CH3COOH} ->[SOCl2] \underset{Ethanoyl chloride}{CH3COCl} ->[NH3 (excess)] \underset{Ethanamide}{CH3CONH2} ->[Br2/KOH][Hofmann bromamide reaction] \underset{Methylamine}{CH3NH2}}\]
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संबंधित प्रश्न
Illustrate the following reaction giving suitable example in each case:Gabriel phthalimide synthesis
Accomplish the following conversion:
Benzyl chloride to 2-phenylethanamine
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]
Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis?
Write the reaction of aromatic primary amine with nitrous acid.
Write the reaction of aliphatic primary amine with nitrous acid.
Give a plausible explanation for the following:
Why are amines less acidic than alcohols of comparable molecular masses?
Mention 'two' uses of propan-2-one.
Give the structures of A, B and C in the following reactions :
Write structures of compounds A and B in each of the following reactions:
Answer in one sentence.
Predict the product of the following reaction.
\[\ce{Nitrobenzene ->[Sn/conc.HCl]?}\]
Answer the following
Explain the ammonolysis of alkyl halides.
Write the order of reactivity of alkyl halides with ammonia.
Alkyl cyanides on reduction by sodium and ethanol give primary amines. This reaction is called as ____________.
Identify the product obtained, when benzamide is treated with bromine and aqueous sodium hydroxide.
Identify the product obtained when benzyl chloride undergoes ammonolysis in presence of excess ammonia followed by the reaction with two moles of methyl iodide.
Which of the following amines exhibits maximum degree of intermolecular hydrogen bonding?
Identify the product obtained when benzamide is treated with bromine and aqueous sodium hydroxide?
The reduction of alkyl cyanide with sodium and ethanol to give primary amines is, ____________.
Identify 'A' and 'B' in the following conversions.
\[\ce{CH3 - I ->[Alc. KCN][\Delta] A ->[Na/C2H5OH] B}\]
Identify product B in the following reaction.
\[\ce{Aniline ->[NaNO2][HCl] A ->[KI] B}\]
Which of the following compounds is obtained when quaternary ammonium hydroxide is strongly heated?
The source of nitrogen in Gabriel synthesis of amines is ______.
Which of the following compounds is the weakest Brönsted base?
Among the following amines, the strongest Brönsted base is:
Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?
Which of the following reactions are correct?
(i)
(ii)
(iii)
(iv)
Suggest a route by which the following conversion can be accomplished.
Identify A and B in the following reaction.
Write following conversions:
acetanilide `->` p-nitroaniline
How will you carry out the following conversion?
How will you carry out the following conversion?
How will you carry out the following conversions?
Match the reactions given in Column I with the statements given in Column II.
| Column I | Column II | ||
| (i) | Ammonolysis | (a) | Amine with lesser number of carbon atoms |
| (ii) | Gabriel phthalimide synthesis | (b) | Detection test for primary amines. |
| (iii) | Hoffmann Bromamide reaction | (c) | Reaction of phthalimide with \[\ce{KOH}\] and \[\ce{R-X}\] |
| (iv) | Carbylamine reaction | (d) | Reaction of alkylhalides with \[\ce{NH3}\] |
Describe Gabriel's phthalimide synthesis. (Give reaction)
Ethylamine can be prepared by the action of bromine and caustic potash on which compound?
Reduction of nitro alkanes yields which compound?
Acetamide and ethyl amide can be distinguished by reacting with.
Which of the following compound is expected to be most basic?
When primary amines are treated with HCl, the product obtained is which of the following?
Which of the following compound gives pink colour on reaction with phthalic anhydride in cone. H2SO4 followed by treatment with NaOH?
- Phenyl methenamine
- N, N - Dimethylaniline
- N - Methyl aniline
- Benzenamine
Choose the correct order of the basic nature of the above amines.
What is the IUPAC name of \[\ce{(CH3)2 - N - CH3}\]?
Identify the product ‘C’ in the following reaction.
\[\ce{Aniline ->[(CH3CH)2O][Pyridine] A ->[Br2][CH3COOH] B ->[H^+ or OH^-] C}\]
Write the name of the product formed by the action of LiAlH4/ether on acetamide.
Write short note on the following:
Ammonolysis
Write a short note on the following:
Ammonolysis
Write a short note on Ammonolysis.
Assertion: Amimonolysis of alkyl halides involves the reaction between alkyl halides and alcoholic ammonia.
Reason: Ammonolysis of alkyl halides produces secondary amines only.
Write a short note on the following:
Ammonolysis
