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प्रश्न
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2Br ->[KCN] A ->[LiAlH4] B ->[HNO2][0^\circ C] C}\]
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उत्तर
\[\ce{\underset{Bromoethane}{CH3CH2Br} ->[KCN] \underset{\underset{(A)}{{Cyanoethane}}}{CH3CH2CN} ->[LiAlH4] \underset{\underset{(B)}{Propan-1-amine}}{CH3CH2CH2NH2} ->[HNO2][0^\circ C] \underset{\underset{(C)}{Propan-1-ol}}{CH3CH2CH2OH}}\]
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संबंधित प्रश्न
Write a short note on the following:
Hoffmann’s bromamide reaction
Give the structure of A, B and C in the following reaction:
\[\ce{CH3CH2I ->[NaCN] A ->[OH-][Partial hydrolysis] B ->[NaOH + Br2] C}\]
Choose the most correct option.
Which of the following compounds will dissolve in aqueous NaOH after undergoing reaction with Hinsberg reagent?
Why cannot aniline be prepared by Gabriel phthalimide synthesis?
Which of the following reactions is appropriate for converting benzamide to aniline?
Which of the following reactions does NOT yield an amine?
Which of the following methods of preparation of amines will give same number of carbon atoms in the chain of amines as in the reactant?
Reduction of nitrobenzene by which of the following reagent gives aniline?
(i) \[\ce{Sn/HCl}\]
(ii) \[\ce{Fe/HCl}\]
(iii) \[\ce{H2 - Pd}\]
(iv) \[\ce{Sn/NH4OH}\]
What is the best reagent to convert nitrile to primary amine?
How will you bring out the following conversion?
Assertion: Hoffmann’s bromamide reaction is given by primary amines.
Reason: Primary amines are more basic than secondary amines.
The Gabriels' phthalimide synthesis is used in the synthesis of
The compound X is which of the following?
\[\ce{CH3CN ->[Na + C2H5OH] x}\]
Reduction of nitro alkanes yields which compound?
Which of the following reaction DOES NOT involve Hoffmann bromamide degradation?
Methyl amine on reaction with chloroform in the presence of NaOH gives ______.
The amine 'A' when treated with nitrous acid gives yellow oily substance. The amine A is ______.
Which of the following would not be a good choice for reducing nitrobenzene to aniline?
Write short note on the following:
Ammonolysis
