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प्रश्न
Tertiary amines have lowest boiling points because ________________
पर्याय
they possess polar N-C bonds
they possess intermolecular dipole-dipole attraction forces
they possess intermolecular H-bonding
they do not possess intermolecular H-bonding
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उत्तर
Tertiary amines have lowest boiling points because they do not possess intermolecular H-bonding
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संबंधित प्रश्न
Identify the weakest base amongst the following :
(a) p- methoxyaniline
(b) o-toluidine
(c) benzene - 1, 4 - diamine
(d) 4 - aminobenzoic acid
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
Arrange the following in increasing order of their basic strength :
C6H5 – NH2, C6H5 – CH2 – NH2, C6H5 – NH – CH3
Arrange the following in increasing order of their basic strength :
- Write structures of different isomeric amines corresponding to the molecular formula C4H11N.
- Write the IUPAC names of all the isomers.
- What type of isomerism is exhibited by different pairs of amines?
How will you convert Benzene into N, N-dimethylaniline?
Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH
Arrange the following in increasing order of their basic strength:
C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2
Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2
Complete the following acid-base reaction and name the product:
\[\ce{CH3CH2CH2NH2 + HCl ->}\]
Complete the following acid-base reaction and name the product:
\[\ce{(C2H5)3N + HCl ->}\]
Account for the following:
Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Arrange the following:
In increasing order of boiling point:
C2H5OH, (CH3)2NH, C2H5NH2
Write a short note on ammonolysis.
Accomplish the following conversion:
Aniline to p-bromoaniline
Give a plausible explanation for the following:
Why are aliphatic amines stronger bases than aromatic amines?
Complete the following reaction:
\[\ce{C6H5N2Cl + H3PO2 + H2O ->}\]
Give reasons CH3NH2 is more basic than C6H5NH2.
Give reason (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
Illustrate the following reactions giving suitable example in each case
Ammonolysis
Arrange the following in increasing order of basic strength :
C6H5NH2, C6H5NHCH3, C6H5N(CH3)2
Choose the most correct option.
Which one of the following compounds has the highest boiling point?
Answer in one sentence.
Arrange the following amines in increasing order of boiling points.
n-propylamine, ethylmethyl amine, trimethylamine.
Which among the following has the highest boiling point?
Which of the following should be most volatile?
Assertion: N-Ethylbenzene sulphonamide is soluble in alkali.
Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.
Account for the following:
N-ethylethanamine boils at 329.3 K and butanamine boils at 350.8 K, although both are isomeric in nature.
Dimerisation of carboxylic acids is due to
Which of the following compound gives a secondary amine oh reduction?
Which of the following have less melting point than amine?
Which of the following amines form maximum hydrogen bonds within themselves?
Which one of the following compounds will liberate CO2, when treated with NaHCO3?
Arrange the following in increasing order of their boiling point:
C2H5OH, C2H5NH2, (C2H5)3N
Arrange the decreasing boiling point.
\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
The correct order of decreasing basic strength of the given amines is:
