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Tertiary amines have lowest boiling points because ________________ - Chemistry

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प्रश्न

Tertiary amines have lowest boiling points because ________________

विकल्प

  • they possess polar N-C bonds

  • they possess intermolecular dipole-dipole attraction forces

  • they possess intermolecular H-bonding

  • they do not possess intermolecular H-bonding

MCQ
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उत्तर

Tertiary amines have lowest boiling points because they do not possess intermolecular H-bonding

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अध्याय 13: Amines - Multiple Choice Questions

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संबंधित प्रश्न

Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.


Arrange the following in increasing order of their basic strength :

C6H5 – NH2, C6H5 – CH2 – NH2, C6H5 – NH – CH3


  1. Write structures of different isomeric amines corresponding to the molecular formula C4H11N.
  2. Write the IUPAC names of all the isomers.
  3. What type of isomerism is exhibited by different pairs of amines?

How will you convert Benzene into aniline?


How will you convert Benzene into N, N-dimethylaniline?


How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?


Arrange the following in increasing order of their basic strength:

CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2


Complete the following acid-base reaction and name the product:

\[\ce{CH3CH2CH2NH2 + HCl ->}\]


Complete the following acid-base reaction and name the product:

\[\ce{(C2H5)3N + HCl ->}\]


Account for the following:

Gabriel phthalimide synthesis is preferred for synthesising primary amines.


Write a short note on ammonolysis.


Accomplish the following conversion:

Benzene to m-bromophenol


Give a plausible explanation for the following:

Why are aliphatic amines stronger bases than aromatic amines?


Complete the following reaction:

\[\ce{C6H5N2Cl + H3PO2 + H2O ->}\]


Give reasons CH3NH2 is more basic than C6H5NH2.


 Arrange the following in the increasing order of their pKvalues:

C6H5NH2, C2H5NH2, C6H5NHCH3


Illustrate the following reactions giving suitable example in each case 

Ammonolysis


Arrange the following in increasing order of basic strength :

C6H5NH2, C6H5NHCH3, C6H5N(CH3)2


Choose the most correct option.

Which one of the following compounds has the highest boiling point?


Answer in one sentence.

Arrange the following amines in increasing order of boiling points.

n-propylamine, ethylmethyl amine, trimethylamine.


Arrange the following compounds in increasing order of their boiling points.

Ethyl alcohol, Ethyl amine, Ethanoic acid, Ethane


The CORRECT decreasing order of solubility in water will be ____________.


Which among the following has the highest boiling point?


The CORRECT decreasing order of boiling points is:


Among the following isomeric amines, an amine having highest boiling point is:


Which of the following should be most volatile?


A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.


Assertion: N-Ethylbenzene sulphonamide is soluble in alkali.

Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.


Acetic acid exist as dimer in benzene due to


Dimerisation of carboxylic acids is due to


The hydrogen bond is shortest in


Which of the following have less melting point than amine?


Arrange the following in increasing order of their boiling point:

C2H5OH, C2H5NH2, (C2H5)3N


Arrange the decreasing boiling point.

\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]


Write short note on the following:

Ammonolysis


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