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प्रश्न
Give reasons CH3NH2 is more basic than C6H5NH2.
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उत्तर
Aromatic amines are far less basic than aliphatic amines. This can be explained as follows:
Resonance stabilisation is there in aniline. It can be regarded as a resonance hybrid of the following structures:
Hence, the lone pair of electrons on the nitrogen atom gets delocalised over benzene ring and thus is less available for protonation.
The electron density on the nitrogen atom is increased by electron-donating inductive effect of the alkyl groups. As a result, aliphatic amines are much stronger bases than aniline.
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संबंधित प्रश्न
Identify the weakest base amongst the following :
(a) p- methoxyaniline
(b) o-toluidine
(c) benzene - 1, 4 - diamine
(d) 4 - aminobenzoic acid
How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?
Arrange the following in increasing order of their basic strength:
CH3NH2, (CH3)2NH, (CH3)3N, C6H5NH2, C6H5CH2NH2
Arrange the following compounds in increasing order of their boiling points.
Ethyl alcohol, Ethyl amine, Ethanoic acid, Ethane
A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.
Dimerisation of carboxylic acids is due to
Which of the following compound gives a secondary amine oh reduction?
Which of the following amines form maximum hydrogen bonds within themselves?
Arrange the following in increasing order of their boiling point:
C2H5OH, C2H5NH2, (C2H5)3N
The correct order of decreasing basic strength of the given amines is:
