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प्रश्न
Arrange the following in increasing order of their basic strength :
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उत्तर
Reason:-
The -CH3 group will increase the electron density on the benzene ring because of its +I effect, while the NO2 group will decrease the electron density on the benzene ring because of its ‒I effect. Hence, the C6H5-NH2 molecule having -CH3 group will be more basic than C6H5-NH2. Also, it will be more basic than the C6H5-NH2 molecule with the NO2 group.
संबंधित प्रश्न
How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?
Arrange the following in increasing order of their basic strength:
C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH
Arrange the following:
In increasing order of boiling point:
C2H5OH, (CH3)2NH, C2H5NH2
Accomplish the following conversion:
Aniline to p-bromoaniline
Complete the following reaction:
\[\ce{C6H5N2Cl + H3PO2 + H2O ->}\]
Give reason (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Assertion: N-Ethylbenzene sulphonamide is soluble in alkali.
Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.
Which of the following amines form maximum hydrogen bonds within themselves?
Which one of the following compounds will liberate CO2, when treated with NaHCO3?
Write short note on the following:
Ammonolysis
