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Question
Arrange the following in increasing order of their basic strength :
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Solution
Reason:-
The -CH3 group will increase the electron density on the benzene ring because of its +I effect, while the NO2 group will decrease the electron density on the benzene ring because of its ‒I effect. Hence, the C6H5-NH2 molecule having -CH3 group will be more basic than C6H5-NH2. Also, it will be more basic than the C6H5-NH2 molecule with the NO2 group.
RELATED QUESTIONS
Arrange the following in increasing order of their basic strength :
C6H5 – NH2, C6H5 – CH2 – NH2, C6H5 – NH – CH3
Arrange the following in increasing order of their basic strength:
C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2
Complete the following acid-base reaction and name the product:
\[\ce{(C2H5)3N + HCl ->}\]
Accomplish the following conversion:
Benzene to m-bromophenol
Arrange the following in increasing order of basic strength :
C6H5NH2, C6H5NHCH3, C6H5N(CH3)2
Among the following isomeric amines, an amine having highest boiling point is:
A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.
Which of the following amines form maximum hydrogen bonds within themselves?
Which one of the following compounds will liberate CO2, when treated with NaHCO3?
Write short note on the following:
Ammonolysis
