Advertisements
Advertisements
प्रश्न
Why does a solution containing non-volatile solute have higher boiling point than the pure solvent ?
Advertisements
उत्तर
Boiling point is the temperature at which the vapour pressure of a substance becomes equal to the atmospheric pressure. According to Raoult's law, the vapour pressure of a solvent decreases in the presence of a non-volatile solute. Thus, the vapour pressure of a solution containing a non-volatile solute requires a high temperature to become equal to the atmospheric pressure. That is why the boiling point of a solution containing a non-volatile solute increases. Thus, the solution containing a non-volatile solute has a higher boiling point than a pure solvent.
संबंधित प्रश्न
In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes?
A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate:
- molar mass of the solute.
- vapour pressure of water at 298 K.
What type of azeotrope is formed by positive deviation from Raoult’s law?
What is meant by negative deviation from Raoult's law? Give an example. What is the sign of ∆mixH for negative deviation?
Raoult’s law states that for a solution of volatile liquids the partial pressure of each component in the solution is ____________.
At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is ______.
Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?
On the basis of information given below mark the correct option.
(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as A–B type interactions.
(B) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type interactions.
(C) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type interactions.
Using Raoult’s law explain how the total vapour pressure over the solution is related to mole fraction of components in the following solutions.
\[\ce{NaCl(s) and H2O(l)}\]
If the weight of the non-volatile solute urea (NH2–CO–NH2) is to be dissolved in 100 g of water, in order to decrease the vapour-pressure of water by 25%, then the weight of the solute will be ______ g.
