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Why Does a Solution Containing Non-volatile Solute Have Higher Boiling Point than the Pure Solvent ? - Chemistry

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प्रश्न

Why does a solution containing non-volatile solute have higher boiling point than the pure solvent ?

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उत्तर

Boiling point is the temperature at which the vapour pressure of a substance becomes equal to the atmospheric pressure. According to Raoult's law, the vapour pressure of a solvent decreases in the presence of a non-volatile solute. Thus, the vapour pressure of a solution containing a non-volatile solute requires a high temperature to become equal to the atmospheric pressure. That is why the boiling point of a solution containing a non-volatile solute increases. Thus, the solution containing a non-volatile solute has a higher boiling point than a pure solvent.

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2014-2015 (March) Patna Set 2

संबंधित प्रश्न

In non-ideal solution, what type of deviation shows the formation of maximum boiling azeotropes?


What is meant by positive deviations from Raoult's law? Give an example. What is the sign of ∆mixH for positive deviation?


Calculate the mass of a non-volatile solute (molar mass 40 g mol−1) which should be dissolved in 114 g octane to reduce its vapour pressure to 80%.


For the reaction :

\[\ce{2NO_{(g)} ⇌ N2_{(g)} + O2_{(g)}}\];

ΔH = -heat

K= 2.5 × 10at 298K

What will happen to the concentration of Nif :

(1) Temperature is decreased to 273 K.

(2) The pressure is reduced


State Raoult’s law for a solution containing volatile components. Write two characteristics of the solution which obey Raoult’s law at all concentrations. 


Minimum boiling azeotrope is formed by the solution which showed


At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is ______.


On the basis of information given below mark the correct option.

(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as A–B type interactions.

(B) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type interactions.

(C) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type interactions.


Two liquids X and Y form an ideal solution. The mixture has a vapour pressure of 400 mm at 300 K when mixed in the molar ratio of 1 : 1 and a vapour pressure of 350 mm when mixed in the molar ratio of 1 : 2 at the same temperature. The vapour pressures of the two pure liquids X and Y respectively are ______.


A solution of a non-volatile solute in water freezes at −0.30°C. The vapour pressure of pure water at 298 K is 23.51 mm Hg and Kf for water is 1.86 degree/mol. The vapour pressure of rain solution at 298 K is ______ mm Hg.


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