मराठी

Why Does a Solution Containing Non-volatile Solute Have Higher Boiling Point than the Pure Solvent ?

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प्रश्न

Why does a solution containing non-volatile solute have higher boiling point than the pure solvent ?

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उत्तर

Boiling point is the temperature at which the vapour pressure of a substance becomes equal to the atmospheric pressure. According to Raoult's law, the vapour pressure of a solvent decreases in the presence of a non-volatile solute. Thus, the vapour pressure of a solution containing a non-volatile solute requires a high temperature to become equal to the atmospheric pressure. That is why the boiling point of a solution containing a non-volatile solute increases. Thus, the solution containing a non-volatile solute has a higher boiling point than a pure solvent.

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2014-2015 (March) Patna Set 2

संबंधित प्रश्‍न

Define azeotropes. 


A solution containing 30 g of non-volatile solute exactly in 90 g of water has a vapour pressure of 2.8 kPa at 298 K. Further, 18 g of water is then added to the solution and the new vapour pressure becomes 2.9 kPa at 298 K. Calculate:

  1. molar mass of the solute.
  2. vapour pressure of water at 298 K.

For the reaction :

\[\ce{2NO_{(g)} ⇌ N2_{(g)} + O2_{(g)}}\];

ΔH = -heat

K= 2.5 × 10at 298K

What will happen to the concentration of Nif :

(1) Temperature is decreased to 273 K.

(2) The pressure is reduced


A solution containing 8.44 g of sucrose in 100 g of water has a vapour pressure 4.56 mm of Hg at 273 K. If the vapour pressure of pure water is 4.58 mm of Hg at the same temperature, calculate the molecular weight of sucrose. 


State Raoult’s law for a solution containing volatile components. Write two characteristics of the solution which obey Raoult’s law at all concentrations. 


An aqueous solution of hydrochloric acid:


The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows ____________.


On the basis of information given below mark the correct option.

(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly same as A–B type interactions.

(B) In ethanol and acetone mixture A–A or B–B type intermolecular interactions are stronger than A–B type interactions.

(C) In chloroform and acetone mixture A–A or B–B type intermolecular interactions are weaker than A–B type interactions.


On the basis of information given below mark the correct option.
On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.


The vapour pressure of pure liquid X and pure liquid Y at 25°C are 120 mm Hg and 160 mm Hg respectively. If equal moles of X and Y are mixed to form an ideal solution, calculate the vapour pressure of the solution.


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