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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

Account for the following: Gabriel phthalimide synthesis is preferred for synthesising primary amines.

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प्रश्न

Account for the following:

Gabriel phthalimide synthesis is preferred for synthesising primary amines.

लघु उत्तर
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उत्तर

Gabriel phthalimide synthesis results in the formation of 1° amine only. 2° or 3° amines are not formed in this synthesis. Thus, a pure 1° amine can be obtained. Therefore, Gabriel phthalimide synthesis is preferred for synthesizing primary amines.

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पाठ 9: Amines - Exercises [पृष्ठ २७८]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 9 Amines
Exercises | Q 9.3 (vii) | पृष्ठ २७८

संबंधित प्रश्‍न

Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.


Give reason for the following:

Primary amines have higher boiling point than tertiary amines.


  1. Write structures of different isomeric amines corresponding to the molecular formula C4H11N.
  2. Write the IUPAC names of all the isomers.
  3. What type of isomerism is exhibited by different pairs of amines?

How will you convert Benzene into aniline?


How will you convert Benzene into N, N-dimethylaniline?


Arrange the following in increasing order of their basic strength:

C2H5NH2, C6H5NH2, NH3, C6H5CH2NH2 and (C2H5)2NH


Arrange the following in increasing order of their basic strength:

C2H5NH2, (C2H5)2NH, (C2H5)3N, C6H5NH2


Arrange the following:

In increasing order of boiling point:

C2H5OH, (CH3)2NH, C2H5NH2


Give reasons CH3NH2 is more basic than C6H5NH2.


 Arrange the following in the increasing order of their pKvalues:

C6H5NH2, C2H5NH2, C6H5NHCH3


Illustrate the following reactions giving suitable example in each case 

Ammonolysis


Arrange the following compounds in increasing order of their boiling points.

Ethyl alcohol, Ethyl amine, Ethanoic acid, Ethane


The CORRECT decreasing order of solubility in water will be ____________.


Among the following isomeric amines, an amine having highest boiling point is:


A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.


Which one of the following compounds will liberate CO2, when treated with NaHCO3?


Arrange the following in increasing order of their boiling point:

C2H5OH, C2H5NH2, (C2H5)3N


The correct order of decreasing basic strength of the given amines is:


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