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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?

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प्रश्न

How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?

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उत्तर

\[\ce{Cl-(CH2)4-Cl ->[2 mol NaCN][EtOH] NC-(CH2)4-CN ->[H2/Ni][Reduction] \underset{Hexan-1, 6-diamine}{H2NH2C-(CH2)4-CH2NH2}}\]

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पाठ 9: Amines - Intext Questions [पृष्ठ २६५]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 9 Amines
Intext Questions | Q 9.3 (iii) | पृष्ठ २६५

संबंधित प्रश्‍न

Identify the weakest base amongst the following :

(a) p- methoxyaniline

(b) o-toluidine

(c) benzene - 1, 4 - diamine

(d) 4 - aminobenzoic acid


Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.


Give reason for the following:

Primary amines have higher boiling point than tertiary amines.


Arrange the following: C2H5NH2, C2H5OH, (CH3)3N – in the increasing order of their boiling point


Accomplish the following conversion:

Benzene to m-bromophenol


Give a plausible explanation for the following:

Why are aliphatic amines stronger bases than aromatic amines?


Complete the following reaction:

\[\ce{C6H5N2Cl + H3PO2 + H2O ->}\]


Give reasons CH3NH2 is more basic than C6H5NH2.


Illustrate the following reactions giving suitable example in each case 

Ammonolysis


Tertiary amines have lowest boiling points because ________________


Which of the following should be most volatile?


A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.


Assertion: N-Ethylbenzene sulphonamide is soluble in alkali.

Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.


Which of the following amines form maximum hydrogen bonds within themselves?


Arrange the following in increasing order of their boiling point:

C2H5OH, C2H5NH2, (C2H5)3N


Arrange the decreasing boiling point.

\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]


The correct order of decreasing basic strength of the given amines is:


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