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कर्नाटक बोर्ड पी.यू.सी.पीयूसी विज्ञान 2nd PUC Class 12

How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?

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प्रश्न

How will you convert Cl−(CH2)4−Cl into hexan-1, 6-diamine?

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उत्तर

\[\ce{Cl-(CH2)4-Cl ->[2 mol NaCN][EtOH] NC-(CH2)4-CN ->[H2/Ni][Reduction] \underset{Hexan-1, 6-diamine}{H2NH2C-(CH2)4-CH2NH2}}\]

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पाठ 9: Amines - Intext Questions [पृष्ठ २६५]

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एनसीईआरटी Chemistry Part 1 and 2 [English] Class 12
पाठ 9 Amines
Intext Questions | Q 9.3 (iii) | पृष्ठ २६५

संबंधित प्रश्‍न

Arrange the following: C2H5NH2, C2H5OH, (CH3)3N – in the increasing order of their boiling point


Complete the following acid-base reaction and name the product:

\[\ce{(C2H5)3N + HCl ->}\]


Account for the following:

Gabriel phthalimide synthesis is preferred for synthesising primary amines.


Arrange the following:

In increasing order of boiling point:

C2H5OH, (CH3)2NH, C2H5NH2


Write a short note on ammonolysis.


Give a plausible explanation for the following:

Why are aliphatic amines stronger bases than aromatic amines?


Complete the following reaction:

\[\ce{C6H5N2Cl + H3PO2 + H2O ->}\]


Give reasons CH3NH2 is more basic than C6H5NH2.


 Arrange the following in the increasing order of their pKvalues:

C6H5NH2, C2H5NH2, C6H5NHCH3


Answer in one sentence.

Arrange the following amines in increasing order of boiling points.

n-propylamine, ethylmethyl amine, trimethylamine.


A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.


Assertion: N-Ethylbenzene sulphonamide is soluble in alkali.

Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.


Account for the following:

N-ethylethanamine boils at 329.3 K and butanamine boils at 350.8 K, although both are isomeric in nature.


Which of the following compound gives a secondary amine oh reduction?


Which of the following have less melting point than amine?


Which one of the following compounds will liberate CO2, when treated with NaHCO3?


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