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प्रश्न
Account for the following:
N-ethylethanamine boils at 329.3 K and butanamine boils at 350.8 K, although both are isomeric in nature.
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उत्तर
Primary and secondary amines are engaged in intermolecular association due to hydrogen bonding between nitrogen of one and hydrogen of another molecule. Due to the presence of three hydrogen atoms, the intermolecular association is more in primary amines than in secondary amines as there are two hydrogen atoms available for hydrogen bond formation in it.
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संबंधित प्रश्न
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Arrange the following in increasing order of their basic strength :
C6H5 – NH2, C6H5 – CH2 – NH2, C6H5 – NH – CH3
Account for the following:
Gabriel phthalimide synthesis is preferred for synthesising primary amines.
Give a plausible explanation for the following:
Why are aliphatic amines stronger bases than aromatic amines?
Answer in one sentence.
Arrange the following amines in increasing order of boiling points.
n-propylamine, ethylmethyl amine, trimethylamine.
The CORRECT decreasing order of boiling points is:
Among the following isomeric amines, an amine having highest boiling point is:
The hydrogen bond is shortest in
Write short note on the following:
Ammonolysis
The correct order of decreasing basic strength of the given amines is:
