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प्रश्न
Which of the following should be most volatile?
पर्याय
\[\ce{(CH3)3N}\]
\[\ce{CH3CH2CH3}\]
\[\ce{CH3CH2CH2NH2}\]
\[\begin{array}{cc}
\ce{CH3CH2}\\
\phantom{..........}\backslash\\
\phantom{...............}\ce{NH}\\
\phantom{...........}/\\\
\phantom{......}\ce{CH3}
\end{array}\]
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उत्तर
\[\ce{CH3CH2CH3}\]
Explanation:
Among primary, secondary and tertiary amines, tertiary amines are the most volatile compounds as they don't have any strong intermolecular H - bonding between \[\ce{N - H}\] like the primary and secondary amines have.
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संबंधित प्रश्न
Give reasons for the following: (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
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Give reasons CH3NH2 is more basic than C6H5NH2.
Give reason (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Arrange the following in the increasing order of their pKb values:
C6H5NH2, C2H5NH2, C6H5NHCH3
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Ammonolysis
Choose the most correct option.
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Tertiary amines have lowest boiling points because ________________
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Reason: Hydrogen attached to nitrogen in sulphonamide is strongly acidic.
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\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
