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प्रश्न
Which of the following should be most volatile?
विकल्प
\[\ce{(CH3)3N}\]
\[\ce{CH3CH2CH3}\]
\[\ce{CH3CH2CH2NH2}\]
\[\begin{array}{cc}
\ce{CH3CH2}\\
\phantom{..........}\backslash\\
\phantom{...............}\ce{NH}\\
\phantom{...........}/\\\
\phantom{......}\ce{CH3}
\end{array}\]
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उत्तर
\[\ce{CH3CH2CH3}\]
Explanation:
Among primary, secondary and tertiary amines, tertiary amines are the most volatile compounds as they don't have any strong intermolecular H - bonding between \[\ce{N - H}\] like the primary and secondary amines have.
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संबंधित प्रश्न
Give reason for the following:
Primary amines have higher boiling point than tertiary amines.
Arrange the following: C2H5NH2, C2H5OH, (CH3)3N – in the increasing order of their boiling point
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- Write the IUPAC names of all the isomers.
- What type of isomerism is exhibited by different pairs of amines?
Arrange the following:
In increasing order of boiling point:
C2H5OH, (CH3)2NH, C2H5NH2
Give reasons CH3NH2 is more basic than C6H5NH2.
Give reason (CH3)2NH is more basic than (CH3)3N in an aqueous solution.
Illustrate the following reactions giving suitable example in each case
Ammonolysis
Arrange the following in increasing order of basic strength :
C6H5NH2, C6H5NHCH3, C6H5N(CH3)2
Answer in one sentence.
Arrange the following amines in increasing order of boiling points.
n-propylamine, ethylmethyl amine, trimethylamine.
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A compound Z with molecular formula \[\ce{C3H9N}\] reacts with \[\ce{C6H5SO2Cl}\] to give a solid, insoluble in alkali. Identify Z.
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The hydrogen bond is shortest in
Which of the following have less melting point than amine?
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Arrange the decreasing boiling point.
\[\ce{CH3COOH, C2H5OH, CH3NH2, CH3OCH3}\]
Write short note on the following:
Ammonolysis
