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Mulliken- Barker's Test: Test of Nitro group

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Estimated time: 2 minutes
CBSE: Class 12

Key Points: Mulliken-Barker's Test: Test for Nitro Group

Used to detect the presence of nitro group (–NO₂)

\[ \mathrm{R} - \mathrm{NO}_2 \xrightarrow[\Delta]{\mathrm{Zn} - \mathrm{NH}_4\mathrm{Cl}} \mathrm{R} - \mathrm{NHOH} \xrightarrow[\text{T.R.}]{\mathrm{AgNO}_3 + \mathrm{NH}_4\mathrm{OH}} \underset{\text{black ppt}}{\mathrm{Ag} \downarrow} \]

This is also called Mulliken's test

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