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Arrhenius Concept of Acids and Bases

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Estimated time: 3 minutes
CBSE: Class 12

Key Points: Arrhenius Concept of Acids and Bases

Acid: Substance that produces H⁺ ions (or H₃O⁺) in aqueous solution.

  • Example: HCl → H⁺ + Cl⁻ ; H₂SO₄ → 2H⁺ + SO₄²⁻

Base: Substance that produces OH⁻ ions in aqueous solution.

  • Example: NaOH → Na⁺ + OH⁻ ; KOH → K⁺ + OH⁻

H⁺ ions don't exist freely — they combine with water to form the hydronium ion (H₃O⁺).

Applicable only in aqueous solutions.

  • Does not explain NH₃ as a base (no OH⁻ group present).
  • Does not explain gas-phase reactions (e.g., HCl + NH₃ → NH₄Cl in the gaseous state).
  • Does not explain why CO₂ and SO₂ show acidic character.
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