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Gas and Vapour

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Estimated time: 13 minutes
  • Introduction
  • Definition: Critical Temperature
  • Definition: Gas
  • Definition: Vapour
  • Critical Temperatures of Common Substances
  • Real-Life Analogies
  • Key Points: Gas and Vapour
Maharashtra State Board: Class 11

Introduction

The terms gas and vapour are frequently used as though they mean the same thing. In scientific usage, however, they are distinct. The key to distinguishing between them is a fundamental property of every substance called its critical temperature. Understanding this distinction is essential for grasping why some substances — like oxygen — cannot be stored as liquids at room temperature without extreme cooling, while others — like water vapour — condense easily.

Maharashtra State Board: Class 11

Definition: Critical Temperature

Critical Temperature (T~c~) is the highest temperature at which a substance can exist in the liquid state. Above this temperature, a substance in the gaseous phase cannot be liquefied by the application of pressure alone, no matter how high that pressure is.

Maharashtra State Board: Class 11

Definition: Gas

A substance which is in the gaseous phase and is above its critical temperature is called a gas.

Maharashtra State Board: Class 11

Definition: Vapour

A substance which is in the gaseous phase and is below its critical temperature is called a vapour.

Maharashtra State Board: Class 11

Critical Temperatures of Common Substances

The table below lists critical temperatures for common gases and water vapour. At room temperature (~25 °C), substances with T~c~ below 25 °C are classified as gases, while those with T~c~ above 25 °C are classified as vapours.

Maharashtra State Board: Class 11

Real-Life Analogies

Real-Life Scenario Concept Illustrated
Steam from a kettle condenses on a cold surface Steam is a vapour — below water's T~c~ of 374 °C — and condenses easily on cooling or compression.
Oxygen cylinders in hospitals require high-pressure equipment O₂ is a gas at room temp (T~c~ = –118 °C) — must be cooled first, then compressed to liquefy.
CO₂ fire extinguisher contains liquid CO₂ CO₂ is near its T~c~ at room temp (31.1 °C) — stored as liquid under pressure, no cooling needed.
Liquid nitrogen for quick-freezing food N₂ is a gas at room temp — requires industrial refrigeration to cool below –147 °C before storage.
Maharashtra State Board: Class 11

Key Points: Gas and Vapour

  • Critical Temperature (T~c~) is the highest temperature at which a substance can exist as a liquid.
  • A substance in the gaseous state above T~c~ is called a gas — it cannot be liquefied by pressure alone.
  • A substance in the gaseous state below T~c~ is called a vapour — it can be liquefied by increasing pressure.
  • Higher T~c~ indicates stronger intermolecular forces of attraction.
  • Both gas and vapour exert pressure; vapour pressure is the pressure in equilibrium with the liquid phase.
  • Liquefaction of a true gas requires cooling below T~c~ first, followed by compression.

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