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Types of Chemical Reactions > Decomposition Reaction

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  • Definition: Decomposition Reaction
  • Definition: Thermal Decomposition
  • Key Points: Decomposition Reaction
CBSE: Class 10
Maharashtra State Board: Class 10

Definition: Decomposition Reaction

A single reactant breaks down to give simpler products. This is a decomposition reaction.

OR

The chemical reaction in which two or more products are formed from a single reactant is a decomposition reaction.

CBSE: Class 10

Definition: Thermal Decomposition

When a decomposition reaction is carried out by heating, it is called thermal decomposition.

CBSE: Class 10
Maharashtra State Board: Class 10

Key Points: Decomposition Reaction

  • Thermal decomposition involves heating a compound to break it into simpler substances, e.g.,
    2Pb(NO₃)₂ ⟶ 2PbO + 4NO₂ + O₂ (brown fumes of NO₂ observed).
  • Electrolytic decomposition uses electricity to decompose compounds, e.g.,
    2H₂O ⟶ 2H₂ + O₂ (Electrolysis of water gives hydrogen and oxygen gases).
  • Photodecomposition occurs when light energy breaks down a compound, e.g.,
    2AgCl ⟶ 2Ag + Cl₂ (white silver chloride turns grey in sunlight).
  • Thermal decomposition of calcium carbonate produces lime (CaO) and CO₂ gas, which turns lime water milky.
  • Decomposition reactions are usually endothermic and require heat, light, or electricity to occur (e.g., the decomposition of ferrous sulphate, calcium carbonate, or sugar).
 
Maharashtra State Board: Class 10

Experiment

1. Aim: To observe and understand decomposition reactions, where a single reactant breaks down into two or more simpler substances.

2. Requirements

  • Apparatus: evaporating dish, test tubes, bent tube, rubber cork, Bunsen burner.
  • Chemicals: sugar, calcium carbonate (CaCO₃), sulphuric acid, freshly prepared lime water.

4. Procedure

Experiment 1: Decomposition of Sugar

  • Take some sugar in an evaporating dish.
  • Heat it using a Bunsen burner and observe the changes.
  • A black residue (carbon) forms, and water (H₂O) vapour is released.

\[\mathrm{C}_{12}\mathrm{H}_{22}\mathrm{O}_{11}\xrightarrow{\mathrm{Heat}}12C+11H_2O\]

Experiment 2: Decomposition of Calcium Carbonate

  • Take some calcium carbonate (CaCO₃) in a test tube.
  • Fit a bent tube into the test tube using a rubber cork.
  • Insert the other end of the bent tube into another test tube containing freshly prepared lime water.
  • Heat the calcium carbonate strongly. The lime water turns milky, indicating the presence of carbon dioxide (CO₂) gas.

\[\mathrm{CaCO}_3(s)\xrightarrow{\Delta}\mathrm{CaO}(s)+\mathrm{CO}_2\uparrow\]

Decomposition of calcium carbonate

Experiment 3: Electrolysis of Water

  1. Pass electric current through acidulated water.
  2. Observe the formation of hydrogen (H₂) and oxygen (O₂) gases.

\[2H_2O(l)\xrightarrow{\text{Electrical Energy}}2H_2\uparrow+O_2\uparrow\]

5. Conclusion: A decomposition reaction occurs when a single reactant breaks down into two or more simpler substances. These reactions can be thermal (heat-driven), electrolytic (electricity-driven), or biological (natural degradation by microorganisms). Decomposition reactions are crucial in nature, industry, and energy production, such as in the formation of biogas from organic waste.

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